Beta-amyrin synthase
β-amyrin synthase (EC 5.4.99.39 , 2,3-oxidosqualene beta-amyrin cyclase , AsbAS1 , BPY , EtAS , GgbAS1 , LjAMY1 , MtAMY1 , PNY , BgbAS ) is an enzyme with systematic name (3S)-2,3-epoxy-2,3-dihydrosqualene mutase (cyclizing, beta-amyrin-forming) .[ 1] [ 2] [ 3] [ 4] [ 5] [ 6] [ 7] [ 8] [ 9] [ 10] [ 11] This enzyme catalyses the following chemical reaction
(3S)-2,3-epoxy-2,3-dihydrosqualene
⇌ ⇌ -->
{\displaystyle \rightleftharpoons }
beta-amyrin
Some organism possess a monofunctional beta-amyrin synthase.
References
^ Abe I, Ebizuka Y, Seo S, Sankawa U (1989). "Purification of squalene-2,3-epoxide cyclases from cell suspension cultures of Rabdosia japonica Hara". FEBS Lett . 249 : 100–104. doi :10.1016/0014-5793(89)80024-9 . S2CID 84003375 .
^ Abe I, Sankawa U, Ebizuka Y (1989). "Purification of 2,3-oxdosqualene:β-amyrin cyclase from pea seedlings" . Chem. Pharm. Bull . 37 : 536–. doi :10.1248/cpb.37.536 .
^ Kushiro T, Shibuya M, Ebizuka Y (August 1998). "Beta-amyrin synthase--cloning of oxidosqualene cyclase that catalyzes the formation of the most popular triterpene among higher plants" . European Journal of Biochemistry . 256 (1): 238–44. doi :10.1046/j.1432-1327.1998.2560238.x . PMID 9746369 .
^ Hayashi H, Huang P, Kirakosyan A, Inoue K, Hiraoka N, Ikeshiro Y, Kushiro T, Shibuya M, Ebizuka Y (August 2001). "Cloning and characterization of a cDNA encoding beta-amyrin synthase involved in glycyrrhizin and soyasaponin biosyntheses in licorice" . Biological & Pharmaceutical Bulletin . 24 (8): 912–6. doi :10.1248/bpb.24.912 . PMID 11510484 .
^ Husselstein-Muller T, Schaller H, Benveniste P (January 2001). "Molecular cloning and expression in yeast of 2,3-oxidosqualene-triterpenoid cyclases from Arabidopsis thaliana". Plant Molecular Biology . 45 (1): 75–92. doi :10.1023/A:1006476123930 . PMID 11247608 . S2CID 20346811 .
^ Iturbe-Ormaetxe I, Haralampidis K, Papadopoulou K, Osbourn AE (March 2003). "Molecular cloning and characterization of triterpene synthases from Medicago truncatula and Lotus japonicus". Plant Molecular Biology . 51 (5): 731–43. doi :10.1023/a:1022519709298 . PMID 12683345 . S2CID 33111263 .
^ Zhang H, Shibuya M, Yokota S, Ebizuka Y (May 2003). "Oxidosqualene cyclases from cell suspension cultures of Betula platyphylla var. japonica: molecular evolution of oxidosqualene cyclases in higher plants" . Biological & Pharmaceutical Bulletin . 26 (5): 642–50. doi :10.1248/bpb.26.642 . PMID 12736505 .
^ Hayashi H, Huang P, Takada S, Obinata M, Inoue K, Shibuya M, Ebizuka Y (July 2004). "Differential expression of three oxidosqualene cyclase mRNAs in Glycyrrhiza glabra" . Biological & Pharmaceutical Bulletin . 27 (7): 1086–92. doi :10.1248/bpb.27.1086 . PMID 15256745 .
^ Kajikawa M, Yamato KT, Fukuzawa H, Sakai Y, Uchida H, Ohyama K (August 2005). "Cloning and characterization of a cDNA encoding beta-amyrin synthase from petroleum plant Euphorbia tirucalli L". Phytochemistry . 66 (15): 1759–66. doi :10.1016/j.phytochem.2005.05.021 . PMID 16005035 .
^ Basyuni M, Oku H, Tsujimoto E, Kinjo K, Baba S, Takara K (October 2007). "Triterpene synthases from the Okinawan mangrove tribe, Rhizophoraceae". The FEBS Journal . 274 (19): 5028–42. doi :10.1111/j.1742-4658.2007.06025.x . PMID 17803686 .
^ Liu Y, Cai Y, Zhao Z, Wang J, Li J, Xin W, Xia G, Xiang F (May 2009). "Cloning and Functional Analysis of a beta-amyrin synthase gene associated with oleanolic acid biosynthesis in Gentiana straminea MAXIM" . Biological & Pharmaceutical Bulletin . 32 (5): 818–24. doi :10.1248/bpb.32.818 . PMID 19420748 .
External links
Activity Regulation Classification Kinetics Types