Arsenide iodide

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

List

formula system space group unit cell Å volume density comment ref
Ca2AsI trigonal R3m a=4.397, c = 22.29, Z = 3 3.76 brown [1][2]
Ca3AsI3 cubic I4132 a=12.42 3.99 colourless [1]
Cu2P1.8As1.2I2 monoclinic P21/c a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16 Cu exchangeable with Ag; band gap 1.2 eV [3]
Ge38As8I8 cubic P43m a=10.611 metallic; water and air stable [4]
Ag2P1.8As1.2I2 monoclinic P21/c a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16 [5]
Sn24As19.3I8 cubic a=22.179 Z=8 black [6]
Sn20.5□3.5As22I8 cubic a=22.1837 low thermal conductivity [7]
Sn24AsxP19.3−xI8 x=0-16 cubic Pm3n a = 10.9358—11.1495 [8]
Sn19.3Cu4.7As22I8 cubic Pm3n a = 11.1736 Z = 1 1394.4 6.236 clathrate; Zintl; diamagnetic [9]
Sn24–x–δInxAs22–yI8 cubic Pm3n a = 11.088 (x = 0) to a = 11.343 (x = 10.7) clathrate [10]
La2AsI2 trigonal P3m1 a=4.3795 c=10.910 5.56 [11]
Hg4AsI5 orthorhombic Cmca a=11.927 b=12.128 c=19.776 Z=8 2859.0 7.025 red [12]
Hg4As2I3 cubic Pa3 a=12.999 Z=8 2196 8.06 black [13]
HgI2⋅As4S4 monoclinic P21/c a=9.433 b=14.986 c=11.624 β=127.72° Z=4 1299 4.509 orange; dec 212 °C [14]
Hg5AsS2I3 monoclinic C2/c a=13.339 b=8.444 c=13.428 β=118.352 Z=4 1331.2 7.599 black; dec 150 °C [15]
Hg3AsSe4I hexagonal P63mc a = 7.6902, c = 9.968 Z=2 red; air stable [16]
[Hg7As4](AgI3)2 cubic Pa a = 13.138 Z = 4 [17][18]
(Hg2As)2(CdI4) monoclinic P21 a=7.945, b=12.934, c=8.094, β=116.898° 741.7 [19]
[Hg7As4I3](SnI3) cubic P213 a = 13.110, Z = 4 2253.2 7.617 black [20]

References

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  11. ^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
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