Andy Murray defeated Tommy Robredo in the final, 3–6, 7–6(9–7), 7–6(10–8) to win the singles tennis title at the 2014 Valencia Open. He saved five championship points en route to the title. This was the second final in five weeks where Murray defeated Robredo after saving championship points, having also done so at the Shenzhen Open.
Mikhail Youzhny was the defending champion, but lost to Thomaz Bellucci in the first round.
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