Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply. Players may hold more than one non-FIFA nationality.
Source: La Liga, ESPN Rules for classification: [2] 1st points; 2nd head-to-head points; Notes:
^Barcelona finished ahead of Real Madrid on head-to-head points: Barcelona 2–1 Real Madrid, Real Madrid 3–4 Barcelona.
^Sevilla automatically qualified for the 2014–15 UEFA Europa League group stage as the defending champions; the berth through their league position was vacated.
^ abVillarreal finished ahead of Real Sociedad on head-to-head points: Villarreal 5–1 Real Sociedad, Real Sociedad 1–2 Villarreal.