Sodium metatungstate

Sodium metatungstate
Identifiers
3D model (JSmol)
EC Number
  • 412-770-9
  • InChI=1S/6Na.H2O.39O.12W/h;;;;;;1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q6*+1;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*-1;;;;;;;;;;;;
    Key: YVQUUPJGDSQKML-UHFFFAOYSA-N
  • O.[O-][W](=O)(=O)[O-].[O-][W](=O)(=O)[O-].[O-][W](=O)(=O)[O-].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+]
Properties
H2Na6O40W12
Molar mass 2985.99 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
The [W12O40]8- cage. Metatungstates feature the doubly protonated derivative of this cage, i.e. [H2W12O40]6-.[1]

Sodium metatungstate is the inorganic compound with the formula Na6[H2W12O40], sometimes written 3Na2WO4·9WO3·H2O. It is also referred to as sodium polytungstate (SPT). This salt has been used in the manufacture of dense aqueous solutions. Sodium metatungstate exists as white solid. The anion is the polyoxotungstate [H2W12O40]6-, which features six-coordinated tungsten(VI) centers interconnected with doubly- and triply bridging oxo ligands.

Due to its very high solubility in water (max. density 3.1 g/cm3), SPT is widely used as to produce "heavy liquid" for gravity separation (sink /float analysis) and density gradient centrifugation. It has significant advantages when compared to zinc chloride solution or the toxic halogenated carbons for sink-swim analysis. Aqueous SPT is non-toxic (unlike the denser Clerici solution), non-flammable, odorless, reusable and additionally it has a low viscosity.[2]

References

  1. ^ Asami, M.; Ichida, H.; Sasaki, Y. (1984). "The structure of hexakis(tetramethylammonium) dihydrogendodecatungstate enneahydrate, [(CH3)4N]6[H2W12O40].9H2O". Acta Crystallographica Section C. 40 (1): 35–37. Bibcode:1984AcCrC..40...35A. doi:10.1107/S0108270184002924.
  2. ^ Munsterman, Dirk; Kerstholt, Susan (1996). "Sodium polytungstate, a new non-toxic alternative to bromoform in heavy liquid separation". Review of Palaeobotany and Palynology. 91 (1–4): 417–422. Bibcode:1996RPaPa..91..417M. doi:10.1016/0034-6667(95)00093-3.

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