Boroselenate

The boroselenates are chemical compounds containing interlinked borate and selenate groups sharing oxygen atoms. Both selenate and borate groups are tetrahedral in shape. They have similar structures to borosulfates and borophosphates. The borotellurates' tellurium atom is much bigger, so TeO6 octahedra appear instead.[1]

List

chem mw crystal system space group unit cell Å volume density comment references
boroseleniteselenate B2Se3O10 monoclinic P21/c a = 4.3466, b = 7.0237, c = 22.1460, β = 94.922°, Z = 4 [2]
hydronium hexasodium boroselenate selenate (H3O)Na6[B(SeO4)4](SeO4) tetragonal I4 a=9.9796, c=18.2614 Zunyite structure [3][1]
tetrapotassium hydrogen boroselenate K4[BSe4O15(OH)] triclinic P1 a=7.5303, b=7.5380, c=42.3659, α=88.740, β=89.971, γ=89.971° Z=6 Zunyite structure [3][1]
Rb3[B(SeO4)3] orthorhombic Ibca a=7.508, b=15.249, c=23.454, Z=8 linear [3][1]
Cs3[B(SeO4)3] monoclinic P21/c a=11.3552, b=7.9893, c=15.7692, β=101.013° Z=4 linear [3][1]

References

  1. ^ a b c d e Daub, Michael; Hillebrecht, Harald (2 January 2015). "The First Boroselenates as new Silicate Analogues". Chemistry - A European Journal. 21 (1): 298–304. doi:10.1002/chem.201404100. PMID 25359585.
  2. ^ Daub, Michael; Scherer, Harald; Hillebrecht, Harald (2015-03-02). "Synthesis, Crystal Structure, and Spectroscopy of the Mixed-Valent Boroseleniteselenate B 2 Se 3 O 10". Inorganic Chemistry. 54 (5): 2325–2330. doi:10.1021/ic502916j. ISSN 0020-1669. PMID 25695146.
  3. ^ a b c d Bruns, Jörn; Höppe, Henning A.; Daub, Michael; Hillebrecht, Harald; Huppertz, Hubert (26 June 2020). "Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds". Chemistry – A European Journal. 26 (36): 7966–7980. doi:10.1002/chem.201905449. PMC 7384169. PMID 31943390.