1,4-Dichlorobenzene (1,4-DCB, p-DCB, or para-dichlorobenzene, sometimes abbreviated as PDCB or para) is an aryl chloride and isomer of dichlorobenzene with the formula C6H4Cl2. This colorless solid has a strong odor. The molecule consists of a benzene ring with two chlorine atoms (replacing hydrogen atoms) on opposing sites of the ring.
It is used as a disinfectant, pesticide, and deodorant, most familiarly in mothballs in which it is a replacement for the more traditional naphthalene because of naphthalene's greater flammability (though both chemicals have the same NFPA 704 rating). It is also used as a precursor in the production of the chemically and thermally resistant polymer poly(p-phenylene sulfide).[3]
p-DCB is produced by chlorination of benzene using ferric chloride as a catalyst:
The chief impurity is the 1,2 isomer. The compound can be purified by fractional crystallization, taking advantage of its relatively high melting point of 53.5 °C; the isomeric dichlorobenzenes and chlorobenzene melt well below room temperature.[3]
p-DCB is used to control moths, molds, and mildew.[4] It also finds use as a disinfectant[3] in waste containers and restrooms and is the characteristic smell associated with urinal cakes. Its usefulness for these applications arises from p-DCB's low solubility in water and its relatively high volatility: it sublimes readily near room temperature.[3]
Nitration gives 1,4-dichloronitrobenzene, a precursor to commercial dyes and pigments.[5] The chloride sites on p-DCB can be substituted with hydroxylamine and sulfide groups. In a growing application, p-DCB is the precursor to the high performance polymer poly(p-phenylene sulfide):[6]
p-DCB is poorly soluble in water and is not easily broken down by soil organisms. Like many hydrocarbons, p-DCB is lipophilic and will accumulate in fatty tissues if consumed by a person or animal.
The United States Department of Health and Human Services (DHHS) and the International Agency for Research on Cancer (IARC) have determined that p-DCB may reasonably be anticipated to be a carcinogen.[7] This has been indicated by animal studies, although a full-scale human study has not been done.[8]
The United States Environmental Protection Agency (EPA) has set a target maximum contaminant level of 75 micrograms of p-DCB per liter of drinking water (75 μg/L),[9] but publishes no information on the cancer risk.[10] p-DCB is also an EPA-registered pesticide.[11] The United States Occupational Safety and Health Administration (OSHA) has set a maximum level of 75 parts of p-DCB per million parts air in the workplace (75 ppm) for an 8-hour day, 40-hour workweek.[12][13]
A mechanism for the carcinogenic effects of mothballs and some types of air fresheners containing p-DCB has been identified in roundworms.[14]
Due to its carcinogenic nature, use of paradichlorobenzene in the European Union is forbidden as an air freshener (since 2005) and in mothballs (since 2008).
Rhodococcus phenolicus is a bacterium species able to degrade dichlorobenzene as its sole carbon source.[15]
酸化チタン(IV) IUPAC名titanium(IV) oxide 別称二酸化チタンチタニア金紅石アナタース板チタン石 識別情報 CAS登録番号 13463-67-7 E番号 E171 (着色料) KEGG C13409 RTECS番号 XR2775000 特性 化学式 TiO2 モル質量 79.87 g/mol 外観 白色固体 密度 4.23 g/cm3 (ルチル)3.78 g/cm3 (アナターゼ) 融点 1870 °C 沸点 2972 °C 熱化学 標準生成熱 ΔfHo -944.7 kJ mol-1(rutile)[1] 標準モルエントロピー…
Canal in the United Kingdom Map of the Worcester & Birmingham Canal and connecting waterways (zoom in for details) vteWorcester and Birmingham Canal Legend BCN Main Line Gas Street Basin (Worcester Bar) Holliday Street aqueduct 86 A4540 Middle Ring Road Edgbaston Tunnel (105 yd) 81 Cross-City Line Dudley Canal Selly Oak Jn Ariel Aqueduct 80 A38 Bristol Road 79 Cross-City line 75 A441 Pershore Road 74 Camp Hill line Stratford-upon-Avon Canal -- Kings …
此条目讲述了韩国正在施工或详细规划阶段的工程。其包含设计阶段的信息,可能与竣工后情況有所出入。无可靠来源供查证的猜测会被移除。 首都圈廣域急行鐵道A路線(GTX-A)韓語原名수도권 광역급행철도 A노선朝鮮漢字首都圈 廣域急行鐵道 A路線文觀部式Sudogwon Gwangyeok Geuphaeng Cheoldo A noseon概覽營運地點 韩国首爾、京畿道服務類型廣域鐵道所屬系統首都圈電鐵首都圈廣
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