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过氧甲醇

过氧甲醇
别名 过氧化甲醇
甲基过氧化氢
识别
CAS号 3031-73-0  checkY
PubChem 18199
SMILES
 
  • COO
性质
化学式 CH4O2
摩尔质量 48.04 g·mol−1
外观 无色液体
密度 0.9967 g/cm3(15 °C)
沸点 46 °C(319 K)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

过氧甲醇是一种有机化合物,化学式为CH3OOH,它是最简单的氢过氧化物英语hydroperoxide,是一种挥发性的无色液体。它是大气中甲烷氧化反应的中间体而有所研究,[1]但它相当易爆,很少直接应用。[2]它可由过氧化苯甲酸甲酯和氧化(三正丁基锡)在乙醚中反应得到。[3]

参考文献

  1. ^ Logan, Jennifer A.; Prather, Michael J.; Wofsy, Steven C.; McElroy, Michael B. Tropospheric chemistry: A global perspective. Journal of Geophysical Research. 1981, 86 (C8): 7210 [2021-07-14]. Bibcode:1981JGR....86.7210L. doi:10.1029/JC086iC08p07210. (原始内容存档于2022-06-24). 
  2. ^ Roger A. Sheldon. Patai, Saul , 编. Syntheses and Uses of Hydroperoxides and Dialkylperoxides. PATAI'S Chemistry of Functional Groups. John Wiley & Sons. 1983. doi:10.1002/9780470771730.ch6. 
  3. ^ Stefan Baj, Anna Chrobok. A New Method for the Synthesis of Primary Hydroperoxides. A Useful Application of Bis(tributyltin) Oxide in the Hydrolysis of Peroxyesters. Synlett. 2001-12-31, 2001 (05): 0623–0624 [2021-07-14]. ISSN 0936-5214. doi:10.1055/s-2001-13365. (原始内容存档于2018-06-05) (英语). 
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