氟化物亚硒酸盐

氟化物亚硒酸盐是一类混合阴离子化合物（英语：Mixed-anion compounds），它同时含有氟离子（F-）和亚硒酸根（SeO32-）离子。

列表

名称 化学式 SeO3:F 分子量 晶系 空间群 晶胞参数（Å） 晶胞体积 密度 光学性质 参考文献
氟化亚硒酸钪 ScSeO3F 1:1 triclinic P1 <13 −173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=2 3.830 [1]
monoclinic P21/m >13 a=4.0643 b =6.6109 c=6.32.35 β=93.298° Z=2 [2]
氟化四亚硒酸三氧三钛三钠 Na3Ti3O3(SeO3)4F 4:1 hexagonal P63 a =12.8439 c =5.2339 SHG 6 × KDP [3]
二氟化亚硒酸二锰 Mn2SeO3F2 1:2 274.83 orthorhombic Pnma a = 7.50848 b = 10.350 and c = 5.47697 Z=4 pink [4]
氟化亚硒酸铁 FeSeO3F 1:1 201.81 monoclinic P21/n a=4.9559 b=5.2023 c=12.040 β=97.87 Z=4 307.50 4.359 yellow [5]
三氟化二亚硒酸二铁铵 NH4Fe2F3(SeO3)2 2:3 [6]
六氟化四亚硒酸四铁哌嗪鎓 [C4N2H12]Fe4F6(SeO3)4 2:3 933.40 monoclinic C2/c a=15.168 b=7.3973 c=16.127 β=90.044 Z=5 1928.9 3.14 brown [6]
六氟化四亚硒酸四铁二乙烯三铵 [C4N3H14]Fe4F6(SeO3)4 2:3 [6]
二氟化亚硒酸二钴 Co2SeO3F2 1:2 282.82 orthorhombic Pnma a = 7.2655 b = 10.001 c = 5.3564 Z=4 389.22 4.826 粉色 [7]
二氟化亚硒酸二镍 Ni2(SeO3)F2 1:2 282.3 orthorhombic Pnma a=7.1727 b=9.9377 c=5.2364 373.25 黄色 [8]
二氟化亚硒酸二铜 Cu2(SeO3)F2 1:2 292.05 orthorhombic Pnma a = 7.066 b = 9.590 c = 5.563 Z=4 377.0 5.146 浅绿色 [9]
二氟化亚硒酸二锌 Zn2(SeO3)F2 1:2 295.70 orthorhombic Pnma a=7.276 b=10.042 c=5.256 Z=4 384.0 5.114 无色 [10]
六氟化亚硒酸二镓三乙烯二铵 C6H14N2Ga2F6SeO3 1:6 494.59 Monoclinic P21/c a=12.616 b=7.2700 c=13.605 β=104.746 Z=4 1206.8 2.722 colourless [11]
三氟化亚硒酸镓乙二铵 C2H10N2GaF3SeO3 1:3 315.80 monoclinic P21/c a=9.1107 b=8.0382 c=10.8302 β=90.045 Z=4 793.1 2.2355 无色 [11]
一水合氟化亚硒酸草酸哌嗪鎓 H2pipGaFSeO3[C2O4]H2O 1:1 409.87 triclinic P1 a=6.377 b=9.2820 c=11.4112 α=66.53 β=77.44 γ=71.89 585.47 2.325 colourless [11]
(C4H15N3)2Ga4F2(SeO3)6(C2O4)·4H2O 6:2 1467.11 triclinic P1 a=8.9941 b=9.4963 c=11.2959 α=77.13 β=68.073 γ=83.776 Z=1 872.17 2.793 colourless [11]
亚硒酸氟化钒酰锶 Sr(VO2F)(SeO3) 316.52 orthorhombic Pbca a=9.7816 b=8.0278 c=12.927 Z=8 1015.07 4.142 yellow [12]
氟化亚硒酸钇 YSeO3F 1:1 monoclinic P21/c <319 a=6.5765 b=6.8971 c=7.1728 β=99.036 Z=4 [13][1][14]
monoclinc P 21/m >319 600° a=6.5840 b=6.9809 c=4.3434 β =95.032 Z=2 3.922 [1]
氟化四亚硒酸三氧三钛三银 Ag3Ti3O3(SeO3)4F 1042.15 hexagonal P63 a=12.8975 c=5.2180 Z=2 751.70 4.604 colourless SHG 2×KDP [15]
二氟化二亚硒酸锆二银 Ag2ZrF2(SeO3)2 598.88 orthorhombic Cmca a=7.3640 b=31.451 c=6.2719 1452.6 5.477 colopurless [15]
二氟化亚硒酸二镉 Cd2(SeO3)F2 1:2 389.76 orthorhombic Pnma a=7.803 b=10.566 c=5.729 Z=4 472.4 5.480 无色 [10]
三氟化亚硒酸乙二铵 C2H10N2InF3SeO3 360.90 monoclinic P21/c a=9.3066 b=8.3012 c=11.2923 Z=4 871.68 2.750 colourless [11]
六氟化二亚硒酸三钪铯 CsSc3F6[SeO3]2 2:6 trigonal P3m1 a = 5.6534 c = 10.6987 Z = 1 [16]
Cs(TiOF)3(SeO3)2 2:3 635.53 hexagonal P63mc a=7.2420 c=11.8152 Z=2 536.65 3.933 Colourless SHG 5xKDP [17]
六氟化二亚硒酸三铁铯 CsFe3(SeO3)2F6 2:6 trigonal P3m1 a=5.459 c=10.537 Z=1 271.9 cyan [18]
Ba(VO2F)(SeO3) 366.24 orthorhombic Pbca a=10.0539 b=8.3967 c=13.174 1112.18 4.375 yellow [12]
氟化亚硒酸镧 LaSeO3F 1:1 monoclinic P21/c a = 18.198 b = 7.1575 c = 8.464 β = 96.89 Z = 12 [19][20]
氟化亚硒酸铈 CeSeO3F 1:1 [13]
六氟化二亚硒酸硒酸四镨 Pr4(SeO3)2(SeO4)F6 2:6 monoclinic C2/c a = 22.305 b = 7.1054 c = 8.356 β = 98.05° Z = 4 浅绿色 [21]
氟化四亚硒酸三镨 Pr3F[SeO3]4 浅绿色 [22]
Pr5F[SiO4]2[SeO3]3 3:1 triclinic P1 a = 7.0114 b = 9.8268 c = 12.8679 α = 70.552 β = 76.904 γ = 69.417° Z = 2 5.511 pale green [22]
氟化四亚硒酸三钕 Nd3(SeO3)4F hexagonal P63mc a=10.515 c=7.1211 [23]
氟化四亚硒酸三钐 Sm3(SeO3)4F hexagonal P63mc a=10.474 c=7.0224 [23]
氟化四亚硒酸三钆 Gd3(SeO3)4F 4:1 hexagonal P63mc a = 10.443 b = 6.9432 Z=2 [24][19]
氟化四亚硒酸三镝 Dy3(SeO3)4F 4:1 1014.34 hexagonal P63mc a=10.360 c=6.8647 Z=2 [19]
氟化亚硒酸钬 HoSeO3F 1:1 monoclinic P21/c a=6.5784 b=6.8873 c=7.1825 β =99.213 Z=4 6.43 [14]
Ho3F[SeO3]4 4:1 hexagonal P63mc a = 10.3024 c = 6.8037 Z = 2 [25]
氟化亚硒酸铒 ErSeO3F 1:1 monoclinic P21/c a=6.5553 b=6.8741 c=7.1516 β =99.020 Z=4 6.54 [14]
Er3F[SiO4][SeO3]2 2:1 orthorhombic Pnna a = 5.8692 b = 15.2931 c = 10.2967 Z = 4 pink [22][26]
氟化亚硒酸铥 TmSeO3F 1:1 monoclinic P21/c a=6.5342 b=68607 c=7.1213 β =98,828 Z=4 6.63 [14]
氟化亚硒酸镱 YbSeO3F 1:1 monoclinic P21/c a=6.5146 b=6.8475 c=7.0924 β =98.637 Z=4 6.77 [14]
氟化亚硒酸镥 LuF[SeO3] 1:1 monoclinic P21/c −173°C: a=6.4839 b=6.8128 c=7.0581 β=98.657 Z=4 308.23 6.916 [13]
triclinic P1 a=6.4486 b=6.8441 c=4.2798 α=94.063 β=98.657 γ=91.895 Z=2 187.04 5.698 [13]
monoclinic P21/m 173°C: a=6.4734 b=6.8702 c=4.2843 β=95.602 Z=2 189.63 5.621 [13]
氟化四亚硒酸三镥 Lu3F(SeO3)4 4:1 1051.75 trigonal P63 a=9.883 c=7.066 Z=2 597.7 5.844 无色，SHG 2.5×KDP [27]
氟化亚硒酸钒酰铅 PbVO2(SeO3)F 1:1 436.09 orthorhombic Pbca a=9.812 b=8.147 c=13.026 Z=8 1041.3 5.563 黄色 [28]
氟化硝酸亚硒酸铅镉 PbCdF(SeO3)(NO3) 1:1 orthorhombic Pca21 a=11.121 b=10.366 c=5.3950 Z=4 621.9 5.634 SHG 2.6×KDP 带隙 4.42 eV [29]
氟化亚硒酸铋 BiFSeO3 1:1 354.94 orthorhombic Pca21 a=6.6774 b=6.8872 c=7.4702 Z=4 343.54 6.862 无色， SHG 13.5×KDP [30]
氟化亚硒酸焦亚硒酸三铋 Bi3(SeO3)3(Se2O5)F 3:1 monoclinic F21 SHG 3×KDP [31]
五氟化亚硒酸二铋钾 KBi2SeO3F5 1:5 679.02 orthorhombic Pbcm a=4.553 b=17.80 c=8.80 Z=4 712.9 6.326 white band gap 4.08 eV [32]
五氟化亚硒酸二铋铷 RbBi2SeO3F5 1:5 725.39 Triclinic P1 a=8.842 b=8.917 c=9.63 α=88.28 β=89.82 γ=89.76 Z=4 758.9 6.349 白色，band gap 4.18 eV [32]
RbBi(SeO3)F2 1:2 459.41 orthorhombic Pnma a=13.251 b=6.073 c=6.780 Z=4 545.6 [33]
Bi4TiO2F4(SeO3)4 4:4 1499.66 monoclinic P21/c a=7.0237 b=6.6824 c=17.3240 β=106.637 Z=2 779.07 6.393 无色 [34]
Bi4NbO3F3(SeO3)4 4:3 1541.67 monoclinic P21/c a=7.0448 b=6.6814 c=17.4051 β=106.931 Z=2 783.73 6.533 colourless [34]
Bi4TeO4F2(TeO3)2(SeO3)2 2:2 1670.64 monoclinic P21/c a=7.0304 b=6.6782 c=17.355 β=106.155 Z=2 782.66 7.089 colourless [34]
Bi2F2(MoO4)(SeO3) 1:2 742.86 monoclinic P21/c a=7.1005 b=9.660 c=12.972 β=12.091 Z=4 753.82 6.546 无色 [34]
Bi2ZrO2F2(SeO3)2 2:2 833.10 triclinic P1 a=5.8047 b=6.3469 c=6.7419 α=77.665 β=71.365 γ=72.795 Z=1 222.87 6.207 无色 [34]
氟化二亚硒酸铋铅 PbBi(SeO3)2F 2:1 orthorhombic Pca21 a=12.9672 b=4.5022 c=11.8221 SHG 10.5×KDP; band gap 3.75 eV [35]

参考文献

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