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二甲苯麝香

二甲苯麝香[1]
IUPAC名
1-tert-Butyl-3,5-dimethyl-2,4,6-trinitrobenzene
识别
CAS号 81-15-2  checkY
PubChem 62329
ChemSpider 56123
SMILES
 
  • CC1=C(C(=C(C(C)=C1N(=O)=O)N(=O)=O)C(C)(C)C)N(=O)=O
UN编号 2956
EINECS 201-329-4
ChEBI 77320
KEGG C19462
MeSH musk+xylene
性质
化学式 C
12
H
15
N
3
O
6
摩尔质量 297.2640 g mol−1 g·mol⁻¹
外观 Yellow crystals
氣味 Musk-like
熔点 110 °C(383 K)
溶解性 150 ng dm−1
log P 4.369
蒸氣壓 9.7 mPa (at 40 °C)
危险性
警示术语 R:R2, R40, R50/53
安全术语 S:S2, S36/37, S46, S60, S61
欧盟分类 爆炸性 E 有害 Xn 有害环境物质 N
相关物质
相关化合物 Musk ambrette
相关化学品 Trinitrotoluene
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二甲苯麝香(英語:Musk xylene,化学名:5-叔丁基-2,4,6-三硝基间二甲苯1-叔丁基-3,5-二甲基-2,4,6-三硝基苯)是一种人工合成麝香,它已被用作各种香水消费品中的固定剂,以及一些化妆品中。

合成

二甲苯麝香可由3,5-二甲基叔丁苯在硝酸-硫酸中直接硝化[2],或和二氧化氮臭氧甲磺酸的催化下于二氯甲烷中反应得到。[3]

参考文献

  1. ^ Section 1.3, European Union Risk Assessment Report (2005), pp. 6–7.
  2. ^ Javad Safaei-Ghomi, Abdolhamid Bamoniri. MODIFIED AND CONVENIENT METHODS FOR THE PREPARATION OF SOME NTTRO MUSKS. Organic Preparations and Procedures International. 2004-04, 36 (2): 188–191 [2020-11-19]. ISSN 0030-4948. doi:10.1080/00304940409355396 (英语). 
  3. ^ Hitomi Suzuki, Takashi Murashima, Kazuhiro Shimizu, Kenkichi Tsukamoto. A non-acid methodology for polynitration of arenes at low temperatures. Journal of the Chemical Society, Chemical Communications. 1991, (15): 1049 [2020-11-19]. ISSN 0022-4936. doi:10.1039/c39910001049 (英语). 
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