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二甲氨基三甲基锡

二甲氨基三甲基锡
别名 三甲基锡基二甲胺
识别
CAS号 993-50-0  checkY
性质
化学式 C5H15NSn
摩尔质量 207.89 g·mol−1
沸点 126 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二甲氨基三甲基锡是一种有机锡化合物,化学式为(CH3)2NSn(CH3)3。它可由三甲基氯化锡二甲氨基锂反应得到。[1]它和反应,可以得到三(三甲基锡基)胺二甲胺[1]它和苯基膦反应,可以得到苯基二(三甲基锡基)膦。[2]它和4,4'-二乙炔基联苯反应,生成4,4'-二(三甲基锡基乙炔基)联苯。[3]

参考文献

  1. ^ 1.0 1.1 1.2 K. Jones, M. F. Lappert. 352. Amino-derivatives of metals and metalloids. Part I. Preparation of aminostannanes, stannylamines, and stannazanes. Journal of the Chemical Society (Resumed). 1965: 1944 [2023-03-15]. ISSN 0368-1769. doi:10.1039/jr9650001944 (英语). 
  2. ^ Achim Bruch, Aiko Fukazawa, Eriko Yamaguchi, Shigehiro Yamaguchi, Armido Studer. Bis(phosphoryl)-Bridged Biphenyls by Radical Phosphanylation: Synthesis and Photophysical and Electrochemical Properties. Angewandte Chemie International Edition. 2011-12-09, 50 (50): 12094–12098 [2023-03-15]. doi:10.1002/anie.201104114. (原始内容存档于2023-03-15) (英语). 
  3. ^ Russo, M.V; Lo Sterzo, C; Franceschini, P; Biagini, G; Furlani, A. Synthesis of highly ethynylated mono and dinuclear Pt(II) tethers bearing the 4,4′-bis(ethynyl)biphenyl (debp) unit as central core. Journal of Organometallic Chemistry. January 2001, 619 (1–2): 49–61. ISSN 0022-328X. doi:10.1016/S0022-328X(00)00533-7. 
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