PCN-224

PCN-224
识别
CAS号 1476810-88-4  checkY
性质
化学式 C144H112N12O64Zr15
摩尔质量 4402.83 g·mol−1
外观 暗紫色晶体[1]
紫色透明晶体（dPCN-224）[2]
密度 0.517 g/cm3（100 K，dPCN-224）[2]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。
PCN-224的扫描电镜图，标尺为2 μm[2]

PCN-224是锆和5,10,15,20-四(4-羧基苯基)卟啉（TCPP）形成的金属有机框架（MOF）之一，其结构可以表示为[Zr6O4(OH)4][TCPP]1.5，其无序变体表示为dPCN-224。[2]它可由四氯化锆、TCPP和苯甲酸在DMF中反应得到。[1]它的理论表面积为2985 m2/g。[3]

参考文献

  1. ^ 1.0 1.1 Dawei Feng, Wan-Chun Chung, Zhangwen Wei, Zhi-Yuan Gu, Hai-Long Jiang, Ying-Pin Chen, Donald J. Darensbourg, and Hong-Cai Zhou. Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination. J. Am. Chem. Soc. 2013, 135, 45, 17105–17110. doi:10.1021/ja408084j.
  2. ^ 2.0 2.1 2.2 2.3 Charlotte Koschnick, Robert Stäglich, Tanja Scholz, Maxwell W. Terban, Alberto von Mankowski, Gökcen Savasci, Florian Binder, Alexander Schökel, Martin Etter, Jürgen Nuss, Renée Siegel, Luzia S. Germann, Christian Ochsenfeld, Robert E. Dinnebier, Jürgen Senker & Bettina V. Lotsch. Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221. Nat Commun 12, 3099 (2021). doi:10.1038/s41467-021-23348-w
  3. ^ Understanding the structure-dependent adsorption behavior of four zirconium-based porphyrinic MOFs for the removal of pharmaceuticals. Microporous and Mesoporous Materials. 2024. doi:10.1016/j.micromeso.2023.112827.