5,15-二(五氟苯基)-10,20-二(4-吡啶基)卟啉

5,15-二(五氟苯基)-10,20-二(4-吡啶基)卟啉
识别
CAS号 268735-00-8  checkY
性质
化学式 C42H18F10N6
摩尔质量 796.62 g·mol−1
外观 深紫色晶体[1]
密度 1.535±0.06 g·cm−3（20 °C）[2]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

5,15-二(五氟苯基)-10,20-二(4-吡啶基)卟啉是一种有机化合物，化学式为C42H18F10N6。它可由五氟苯基二(2-吡咯基)甲烷和4-吡啶甲醛在三氟乙酸的存在下于二氯甲烷中反应得到[3]，或直接在丙酸中反应制得。[1]它可以和过渡金属形成配位化合物。[1][4]

参考文献

  1. ^ 1.0 1.1 1.2 Weixia Xu, Zengqi Zhang, Xin Zhao, Jun Li. Catalytically active metal organic framework based on a porphyrin modified by electron-withdrawing groups. Journal of Coordination Chemistry. 2017-02-16, 70 (4): 746–755 [2021-07-03]. ISSN 0095-8972. doi:10.1080/00958972.2016.1267728 （英语）. 
  2. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-07-03].
  3. ^ Jagadeesan Ramesh, Subramaniam Sujatha, Chellaiah Arunkumar. Synthesis, structure, electrochemical, DNA interaction and antimicrobial studies of fluorinated trans-dicationic pyridinium porphyrins. RSC Advances. 2016, 6 (68): 63271–63285 [2021-07-03]. ISSN 2046-2069. doi:10.1039/C6RA09148B （英语）. 
  4. ^ Splan, Kathryn E.; Stern, Charlotte L.; Hupp, Joseph T. Two coordinatively linked supramolecular assemblies constructed from highly electron deficient porphyrins. Inorganica Chimica Acta. 2004, 357 (13): 4005–4014. ISSN 0020-1693. doi:10.1016/j.ica.2004.06.059. 

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