2,6-二甲酰基-4-甲基苯酚
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别名
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2-hydroxy-5-methylisophthalaldehyde, 2-hydroxy-5-methyl-1,3-benzenedicarboxaldehyde
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识别
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CAS号
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7310-95-4 Y
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性质
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外观
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白色固体
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熔点
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113 °C(386 K)[1]
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若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。
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2,6-二甲酰基-4-甲基苯酚是一种有机化合物,化学式为CH3C6H2(CHO)2OH,它是基于4-甲基苯酚最常见的异构体。它是白色固体,可通过瑞穆尔-悌曼反应制得。它可以和胺缩合,得到二亚胺配体。[2][3]
参考文献
- ^ Alois Zinke, Franz Hanus, Erich Ziegler. Beitrag zur Kenntnis des Härtungsprozesses von Phenol-Formaldehyd-Harzen. (Bearbeitet mit Franz Sperk, Herbert Troger u. Erwin Weinhardt). Journal für Praktische Chemie. 1939-03-24, 152 (3-6): 126–144 [2021-02-02]. doi:10.1002/prac.19391520304 (英语).
- ^ Thompson, Laurence K.; Mandal, Sanat K.; Tandon, Santokh S.; Bridson, John N.; Park, Murray K. Magnetostructural Correlations in Bis(μ2-phenoxide)-Bridged Macrocyclic Dinuclear Copper(II) Complexes. Influence of Electron-Withdrawing Substituents on Exchange Coupling. Inorganic Chemistry. 1996, 35 (11): 3117–3125. PMID 11666507. doi:10.1021/IC9514197.
- ^ Gagne, R. R.; Spiro, C. L.; Smith, T. J.; Hamann, C. A.; Thies, W. R.; Shiemke, A. D. The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent copper(I)copper(II) complex. Journal of the American Chemical Society. 1981, 103 (14): 4073–4081. doi:10.1021/ja00404a017.