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1-氧杂-4-硫杂环己烷
| 1-氧杂-4-硫杂环己烷
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IUPAC名
1,4-Oxathiane
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| 别名
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1,4-Thioxane; p-Thioxane; 1-Oxa-4-thiacyclohexane
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| 识别
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| CAS号
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15980-15-1  Y
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| 性质
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| 化学式
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C4H8OS
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| 摩尔质量
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104.17 g·mol−1
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| 熔点
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30 °C（303 K）[1]
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| 沸点
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147—149 °C（420—422 K）[2]
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| 危险性
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GHS危险性符号
 
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| GHS提示词
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Warning
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| H-术语
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H226, H315, H319, H335
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| P-术语
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P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+352, P303+361+353, P304+340, P305+351+338
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| 致死量或浓度：
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2830 mg/kg oral rat
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| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。
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1-氧杂-4-硫杂环己烷是一种有机化合物，化学式为C4H8OS。它可由2,2'-二氯乙醚（或2,2'-二溴乙醚）和硫氢化钾反应得到，[3]或由硫代二甘醇和丁基三氯化锡反应制得。[4]在催化下，它可以被过氧化氢氧化为亚砜或砜。[5]
参考文献
- ^ James Ranald Alexander, Hamilton McCombie. CCLIX.—The reactions of divinyl sulphide, sulphoxide, and sulphone. J. Chem. Soc. 1931, 0 (0): 1913–1918 [2022-05-30]. ISSN 0368-1769. doi:10.1039/JR9310001913 （英语）.
- ^ Frederick Richter, Frederick B. Augustine, Emil Koft, E. Emmet Reid. The Condensation of 2-Hydroxyethyl Sulfides with Alcohols and Phenols 1. Journal of the American Chemical Society. 1952-08, 74 (16): 4076–4079 [2022-05-30]. ISSN 0002-7863. doi:10.1021/ja01136a031. （原始内容存档于2022-05-30） （英语）.
- ^ Movsumzade, M. M.; Gurbanov, P. A.; Askerov, N. D.; Khodzhaev, G. Kh. Reaction of β,β'-dihalodialkyl ethers with potassium hydrosulfide（俄文）. Azerbaidzhanskii Khimicheskii Zhurnal, 1979. 6: 86-90. ISSN 0005-2531.
- ^ Giuseppe Tagliavini, Daniele Marton, Donatella Furlani. Organotins as etherfication catalysts. 11. catalytic conversion of alcohols to open-chain and cyclic ethers by organotin trichlorides. Tetrahedron. 1989-01, 45 (4): 1187–1196 [2022-05-30]. doi:10.1016/0040-4020(89)80027-4. （原始内容存档于2022-07-09） （英语）.
- ^ Elena Badetti, Alessandro Bonetto, Francesco Romano, Luciano Marchiò, Cristiano Zonta, Giulia Licini. Synthesis, Characterization and Catalytic Activity of a Tungsten(VI) Amino Triphenolate Complex. Catalysis Letters. 2017-09, 147 (9): 2313–2318 [2022-05-30]. ISSN 1011-372X. doi:10.1007/s10562-017-2144-z （英语）.
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