高铼酸镍

高铼酸镍
IUPAC名
铼(VII)酸镍(II)
别名 偏高铼酸镍
识别
CAS号 14012-87-4(无水)  checkY
68289-62-3(二水)  checkY
35723-19-4(四水)  checkY
性质
化学式 Ni(ReO4)2
摩尔质量 559.107(无水)
595.139(二水)
631.171(四水) g·mol⁻¹
外观 黄色固体
亮绿色固体
绿色固体[1]
密度 3.95 g·cm-3(四水)
溶解性 310 g(无水)
408 g(二水)
567 g(四水)
相关物质
其他阴离子 高锰酸镍
高氯酸镍
其他阳离子 高铼酸钾
高铼酸亚铁
高铼酸钴
相关化学品 七氧化二铼
高铼酸
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高铼酸镍是一种无机化合物化学式为Ni(ReO4)2

制备

高铼酸溶液溶解镍的氢氧化物或碳酸盐,得到高铼酸镍。[1]

化学性质

高铼酸镍在炽热时分解,生成一氧化镍七氧化二铼[2]

Ni(ReO4)2 → NiO + Re2O7

参考资料

  1. ^ 1.0 1.1 The Salts of Perrhenic Acid. II. The Iron Family and Manganese. William T. Smith , Grover E. Maxwell. J. Am. Chem. Soc., 1949, 71 (2), pp 578–580. DOI:10.1021/ja01170a056
  2. ^ 《无机化学丛书》. 第九卷 锰分族 铁系 铂系. 谢高阳 等主编. 科学出版社. 3.13.3 含氧酸及其盐类. P116

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