溴化镉铯(CsCdBr3)是一种合成晶体材料。它属于AMX3组(A = 碱金属,M = 二价金属,X = 卤素离子)。与大部分其他溴化物不同,CsCdBr3不吸湿,[2]因此它可以用作太阳能电池中的高效上转换材料。[3]因为它具有掺杂稀土金属离子的单晶结构,它也可以用作激活激光媒质。它在可见光和红外区非常透明,可以用作非线性光学晶体。[4]
化学式为Cs2CdBr4的溴化镉铯也已合成。[5]
参考文献
- ^ Persson, Kristin. 36 Materials Science. Materials Data on CsCdBr3 (SG:221) by Materials Project (Data Set). LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). 2014. doi:10.17188/1275593.
- ^ Barthem, R. B.; Buisson, R.; Vial, JC.; Chaminade, JP. ENERGY TRANSFER IN CsCdBr3 : Nd3+SYSTEM (PDF). Le Journal de Physique Colloques. 1985, 46: C7–113–C7–117 [2022-01-01]. doi:10.1051/jphyscol:1985722. (原始内容存档 (PDF)于2022-01-01).
- ^ Cockroft, Nigel J.; Jones, Glynn D.; Nguyen, Dinh C. Dynamics and spectroscopy of infrared-to-visible upconversion in erbium-doped cesium cadmium bromide (CsCdBr3:Er3+). Physical Review B. 1992, 45 (10): 5187–5198. Bibcode:1992PhRvB..45.5187C. PMID 10000233. doi:10.1103/PhysRevB.45.5187.
- ^ Ren, Peng; Qin, Jingui; Chen, Chuangtian. A Novel Nonlinear Optical Crystal for the IR Region: Noncentrosymmetrically Crystalline CsCdBr3and its Properties. Inorganic Chemistry. 2003, 42 (1): 8–10. PMID 12513072. doi:10.1021/ic025813y.
- ^ Altermatt, D.; Arend, H.; Gramlich, V.; Niggli, A.; Petter, W. Low-temperature phases in Cs2CdBr4and Cs2HgBr4. Acta Crystallographica Section B. 1984, 40 (4): 347–350. doi:10.1107/S0108768184002275.