一硒化钚是一种无机化合物，化学式为PuSe，它可以形成黑色晶体，难溶于水。[1][2]它可由三硒化二钚和三氢化钚反应得到，或由化学计量比的单质化合得到：
一硒化钚是立方晶系晶体，空间群Fm3m，晶胞参数a = 0.57934 nm，Z = 4，有NaCl结构。[3]它在高压下发生相变，在20 GPa形成三方相，35 GPa形成立方CsCl相。[4]其磁化率遵循居里-外斯定律。[5]
参考文献
- ^ Eyring, LeRoy; O'Keeffe, Michael. The Chemistry of Extended Defects in Non-metallic Solids: Proceedings of the Institute for Advanced Study on the Chemistry of Extended Defects in Non-Metallic Solids, Casa Blanca Inn, Scottsdale, Arizona, April 16-26, 1969. North-Holland Publishing Company. 1970: 140 [6 August 2021]. ISBN 978-0-7204-0164-6 （英语）.
- ^ Burke, Robert. Hazardous Materials Chemistry for Emergency Responders. CRC Press. 17 June 2013: 85 [6 August 2021]. ISBN 978-1-4398-4986-6. （原始内容存档于2022-05-10） （英语）.
- ^ WebElements Periodic Table » Plutonium » plutonium selenide. webelements.com. [6 August 2021]. （原始内容存档于2021-12-25）.
- ^ Gensini, M.; Gering, E.; Heathman, S.; Benedict, U.; Spirlet, J. C. High-pressure phases of plutonium monoselenide studied by X-ray diffraction. High Pressure Research. 1 April 1990, 2 (5–6): 347–359 [6 August 2021]. ISSN 0895-7959. doi:10.1080/08957959008203187. （原始内容存档于2022-01-18）.
- ^ Macintyre, Jane E. Dictionary of Inorganic Compounds. CRC Press. 23 July 1992: 3783 [6 August 2021]. ISBN 978-0-412-30120-9. （原始内容存档于2022-03-26） （英语）.
拓展阅读
- Takahiro Maehira, Eijiro Sakai, Yasutomi Tatetsu. Electronic structures of of PuX (X=S, Se, Te). Journal of the Korean Physical Society. 2013-08, 63 (3): 809–811 [2021-08-08]. ISSN 0374-4884. doi:10.3938/jkps.63.809 （英语）.
- X. Zhang, H. Zhang, J. Wang, C. Felser, S.-C. Zhang. Actinide Topological Insulator Materials with Strong Interaction. Science. 2012-03-23, 335 (6075): 1464–1466 [2021-08-08]. ISSN 0036-8075. doi:10.1126/science.1216184 （英语）.
