一氟硅烷 是一种无机化合物 ,化学式SiH3F 。
制备
一氟硅烷可以由氟甲烷和硅 反应而成。 [3] 它也可以由氯硅烷 和三氟化锑 反应而成。[4]
性质
一氟硅烷是一种无色气体。[1] 一氟硅烷在96 K时为固体,具有空间群 P21/n的单斜晶体结构,并在常压下直接转变为气态。 [5]
参考资料
- ^ 1.0 1.1 1.2 William M. Haynes. CRC Handbook of Chemistry and Physics, 93rd Edition. CRC Press. 2016: 87. ISBN 978-1-4398-8050-0.
- ^ Dale L. Perry. Handbook of Inorganic Compounds, Second Edition. CRC Press. 2016: 179. ISBN 978-1-4398-1462-8.
- ^ Han-Gook Cho: Investigation of Reaction Paths from Si + CH4 to C + SiH4 and from Si + CH3F to C + SiH3F: Intrinsic Reaction Coordinate Studies. In: Journal of the Korean Chemical Society. 60, 2016, S. 149, doi:10.5012/jkcs.2016.60.2.149
- ^ C. C. Addison. Inorganic Chemistry of the Main-Group Elements. Royal Society of Chemistry. 1973: 188. ISBN 978-0-85186-752-6.
- ^ A. J. Blake, E. A. V. Ebsworth, S. G. D. Henderson, A. J. Welch: Structure of silyl fluoride, SiH3F, at 96 K. In: Acta Crystallographica Section C Crystal Structure Communications. 41, S. 1141, doi:10.1107/S0108270185006904.