(S)-limonen 3-monooksigenaza

(S)-limonen 3-monooksigenaza
Identifikatori
EC broj 1.14.13.47
CAS broj 138066-92-9
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB RCSB PDB PDBe PDBj PDBsum

(S)-limonen 3-monooksigenaza (EC 1.14.13.47, (-)-limonenska 3-hidroksilaza, (-)-limonenska 3-monooksigenaza, (-)-limonen,NADPH:kiseonik oksidoreduktaza (3-hidroksilacija)) je enzim sa sistematskim imenom (S)-limonen,NADPH:kiseonik oksidoreduktaza (3-hidroksilacija).[1] Ovaj enzim katalizuje sledeću hemijsku reakciju

(S)-limonen + NADPH + H+ + O2 (-)-trans-izopiperitenol + NADP+ + H2O

Ovaj enzim ima visoku specifičnost. On može da koristi NADH umesto NADPH, ali je reakcija spora. On je hem-tiolatni protein (P-450).

Reference

  1. ↑ Karp, F., Mihaliak, C.A., Harris, J.L. and Croteau, R. (1990). „Monoterpene biosynthesis: specificity of the hydroxylations of (-)-limonene by enzyme preparations from peppermint (Mentha piperita), spearmint (Mentha spicata), and perilla (Perilla frutescens) leaves”. Arch. Biochem. Biophys. 276: 219-226. PMID 2297225. 

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