(-)-Izopiperitenone reduktaza

(-)-Izopiperitenone reduktaza
Identifikatori
EC broj 1.3.1.82
IntEnz IntEnz view
BRENDA BRENDA entry
ExPASy NiceZyme view
KEGG KEGG entry
MetaCyc metabolic pathway
PRIAM profile
PDB RCSB PDB PDBe PDBj PDBsum

(-)-Izopiperitenone reduktaza (EC 1.3.1.82, (-)-izopiperitenonska reduktaza) je enzim sa sistematskim imenom (+)-cis-izopulegon:NADP+ oksidoreduktaza.[1][2] Ovaj enzim katalizuje sledeću hemijsku reakciju

(+)-cis-izopulegon + NADP+ (-)-izopiperitenon + NADPH + H+

Ova reakcija teče u reverznom smeru. Enzim učestvuje u putu mentolne biosinteze kod Mentha biljki. (+)-pulegon, (+)-cis-isopulegon i (-)-menton nisu supstrati.

Reference

  1. ↑ Croteau, R. and Venkatachalam, K.V. (1986). „Metabolism of monoterpenes: demonstration that (+)-cis-isopulegone, not piperitenone, is the key intermediate in the conversion of (-)-isopiperitenone to (+)-pulegone in peppermint (Mentha piperita)”. Arch. Biochem. Biophys. 249: 306-315. PMID 3755881. 
  2. ↑ Ringer, K.L., McConkey, M.E., Davis, E.M., Rushing, G.W. and Croteau, R. (2003). „Monoterpene double-bond reductases of the (-)-menthol biosynthetic pathway: isolation and characterization of cDNAs encoding (-)-isopiperitenone reductase and (+)-pulegone reductase of peppermint”. Arch. Biochem. Biophys. 418: 80-92. PMID 13679086. 

Literatura

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