Potenciometria

Potenciometria ou método potenciométrico de análise química são métodos que baseiam-se na medida da diferença de potencial de uma célula eletroquímica na ausência de corrente. É um método utilizado para detectar o ponto final de titulações específicas (chamada, pelo uso do método, de titulação potenciométrica), ou para a determinação direta de um determinado constituinte em uma amostra, através da medida do potencial de um eletrodo íon-seletivo, aquele que é sensível exatamente ao íon em análise.

Por se tratar de um equipamento simples e relativamente barato, sendo constituído de um eletrodo de referência, um eletrodo indicador e um dispositivo para leitura do potencial (potencímetro) a estes ligados, e dispensar o uso de indicadores que podem muitas vezes não serem possíveis de ter sua alteração de cor detectável, tornou-se um método difundido e confiável a ser aplicado nas volumetrias, em química analítica quantitativa. Por também permitir a determinação direta de determinadas e específicas substâncias, dispensando as vidrarias e reagentes usados em diversas volumetrias clássicas, se igualmente difundido pelo crescente desenvolvimento e redução de custos da eletrônica..

Referências

  • POTENCIOMETRIA - Universidade Federal do Pará - www.ufpa.br
  • BASSETT, J.; DENNEY, R. C.; JEFFERY, G. H. & MENDHAN, J., VOGEL Análise inorgânica quantitativa,., Editora Guanabara S.A., Rio de Janeiro, 1992.
  • OHLWEILER, O. A., Química analítica quantitativa, 3a ed., Livros Técnicos e Científicos Editora S.A., Rio de Janeiro, 1982, vol. 1 e vol. 2.

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