Espiguetidina

 
(ξ)-Espiguetidina
Nombre IUPAC
5,6,7,7a-Tetrahidro-7-metilbenzo[d]-1,3-dioxolo[4,5-g]pirido[4,3,2-jk][2]benzazepin-11-ol
General
Fórmula estructural Imagen de la estructura
Fórmula molecular C18H16N2O3
Identificadores
Número CAS 112494-57-2[1]​
PubChem 183516
InChI=InChI=1S/C18H16N2O3/c1-20-5-4-10-7-14-17(23-9-22-14)16-13-3-2-12(21)6-11(13)8-19-18(20)15(10)16/h2-3,6-8,18,21H,4-5,9H2,1H3
Key: FHIDFFNXBQHJEV-UHFFFAOYSA-N
Propiedades físicas
Masa molar 308,336 g/mol
Valores en el SI y en condiciones estándar
(25 ℃ y 1 atm), salvo que se indique lo contrario.
[editar datos en Wikidata]

La espiguetidina es una alcaloide benzo[d]-1,3-dioxolo[4,5-g]pirido[4,3,2-jk][2]benzazepínico aislado de la corteza de la planta boliviana Duguetia spixiana (Annonaceae)[2]​

Derivados

 Nombre    Derivado    Fórmula molecular    CAS   Masa molecular (g/mol)   Estado   Fuente natural    Otras propiedades  
Espiguetina Metil éter C19H18N2O3 112494-56-1 322.363 Aislado de Duguetia spixiana (Annonaceae) junto a la espiguetidina. [α]D = -2 ( c, 0.15 in EtOH)
Dragabina Desoxi CHNO 107030-45-5 292.337 Sólido amorfo Aislado de Guatteria sagotiana (Annonaceae)[3]​ Rotación óptica no significativa.
Norgrabidina Desoxi, N-desmetil CHNO 107030-44-4 278.310 Aislado de la corteza del tronco de Meiogyne virgata

Referencias

  1. ↑ Número CAS
  2. ↑ Rasamizafy, S. et al., J. Nat. Prod., 1987, 50, 674
  3. ↑ Cassels, B.K. et al., Chem. Comm., 1986, 1481


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