Virginiamycin S1

Virginiamycin S1
Names
Systematic IUPAC name
N-[(6R,9S,10R,13S,15aS,22S,24aS)-22-Benzyl-6-ethyl-10,23-dimethyl-5,8,12,15,17,21,24-heptaoxo-13-phenyldocosahydro-12H-pyrido[2,1-f]pyrrolo[2,1-l] [1,4,7,10,13,16]oxapentaazacyclononadecin-9-yl]-3-hydroxypyridine-2-carboxamide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.041.314 Edit this at Wikidata
UNII
  • InChI=1S/C43H49N7O10/c1-4-29-40(56)49-21-12-17-30(49)41(57)48(3)32(23-26-13-7-5-8-14-26)42(58)50-22-19-28(51)24-31(50)37(53)47-35(27-15-9-6-10-16-27)43(59)60-25(2)34(38(54)45-29)46-39(55)36-33(52)18-11-20-44-36/h5-11,13-16,18,20,25,29-32,34-35,52H,4,12,17,19,21-24H2,1-3H3,(H,45,54)(H,46,55)(H,47,53)/t25-,29-,30+,31+,32+,34+,35+/m1/s1 ☒N
    Key: FEPMHVLSLDOMQC-IYPFLVAKSA-N ☒N
  • InChI=1/C43H49N7O10/c1-4-29-40(56)49-21-12-17-30(49)41(57)48(3)32(23-26-13-7-5-8-14-26)42(58)50-22-19-28(51)24-31(50)37(53)47-35(27-15-9-6-10-16-27)43(59)60-25(2)34(38(54)45-29)46-39(55)36-33(52)18-11-20-44-36/h5-11,13-16,18,20,25,29-32,34-35,52H,4,12,17,19,21-24H2,1-3H3,(H,45,54)(H,46,55)(H,47,53)/t25-,29-,30+,31+,32+,34+,35+/m1/s1
    Key: FEPMHVLSLDOMQC-IYPFLVAKBH
  • O=C([C@H](CC2=CC=CC=C2)N(C)[C@]([C@H]6N(CCC6)C5=O)=O)N1[C@H]([C@](N[C@H](C(O[C@H](C)[C@@H](C(N[C@@H]5CC)=O)NC(C4=NC=CC=C4O)=O)=O)[C@]3=CC=CC=C3)=O)CC(CC1)=O
Properties
C43H49N7O10
Molar mass 823.904 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Virginiamycin S1 is a macrolide antibiotic in the group of antibiotics known as streptogramin B.[1]

References

  1. ^ Kingston, David G. I.; Molinero, Anthony A.; Purvis, Michael B.; Reed, Josephine W.; LeFevre, Joseph W. (1989). "Studies in the biosynthesis of antibiotics of the virginiamycin family". Revista Latinoamericana de Química. 20 (3–4): 128–132.{{cite journal}}: CS1 maint: multiple names: authors list (link)


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