Ultrafast X-ray diffraction (time-resolved X-ray diffraction) can surpass ultrashortpulse visible techniques, which are limited to detecting structures on the level of valence and free electrons. Ultrashort pulse X-ray techniques are able to resolve atomic scales, where dynamic structural changes and reactions occur in the interior of a material.[3][4][5][6]
Philip H. Bucksbaum; Ryan Coffee; Nora Berrah (2011). "The First Atomic and Molecular Experiments at the Linac Coherent Light Source X-Ray Free Electron Laser". In E. Arimondo; P.R. Berman; C.C. Lin (eds.). Advances in Atomic, Molecular, and Optical Physics. Advances In Atomic, Molecular, and Optical Physics. Vol. 60. Academic Press. pp. 239–289. Bibcode:2011AAMOP..60..239B. doi:10.1016/B978-0-12-385508-4.00005-X. ISBN9780123855084.
Diagram of the table-top ultrafast X-ray diffractometer