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Triazolate

Triazolate
Names
IUPAC name
1,2-diaza-4-azanidacyclopenta-2,5-diene
Identifiers
3D model (JSmol)
Abbreviations tz
ChemSpider
  • InChI=1S/C2H2N3/c1-3-2-5-4-1/h1-2H/q-1
    Key: OCYPXODIXIRXRC-UHFFFAOYSA-N
  • 1,2,3: InChI=1S/C2H2N3/c1-2-4-5-3-1/h1-2H/q-1
    Key: KLUPXSZYZIVRAV-UHFFFAOYSA-N
  • 1,2,4: C1=NN=C[N-]1
  • 1,2,3: C1=N[N-]N=C1
Properties
C2H2N3−
Molar mass 68.060 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

A triazolate is a salt derived from a triazole by the replacement of a proton with a cation. Different isomers exist 1,2,4-triazolate or 1,2,3-triazolate, both are unsaturated heterocyclic ring compounds containing three nitrogen atoms. The basic formula is C2N3H2−. It can be abbreviated by "tz".[1]

Known compounds include zinc,[2] and natural copper minerals, chanabayaite and triazolite.[3]

Trizolate is a tridentate ligand, and can form complexes with metals via the three nitrogen atoms. This enables polymers or metal organic framework compounds to be formed. Triazolate can also be substituted on its carbon atoms.[4]

References

  1. ^ Katritzky, Alan R., ed. (2002). Organometallic Complexes of Pyrazolylborates and Related Ligands. Advances in Heterocyclic Chemistry. Vol. 81. Academic Press. p. 167. doi:10.1016/S0065-2725(01)81012-6. ISBN 9780080493572.
  2. ^ Zhu, AX; Lin, JB; Zhang, JP; Chen, XM (20 April 2009). "Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties". Inorganic Chemistry. 48 (8): 3882–9. doi:10.1021/ic802446m. PMID 19326894.
  3. ^ "Chanabayaite: Chanabayaite mineral information and data". www.mindat.org.
  4. ^ Kobrsi, Issam (2014). "Aluminum Dimer Containing Bulky 1,2,3-Triazolate Ligand". Journal of Chemistry. 2014: 1–6. doi:10.1155/2014/619196.Open access icon

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