Tin(IV) iodate

Tin(IV) iodate
Names
IUPAC name
triiodyloxystannyl iodate
Identifiers
3D model (JSmol)
  • InChI=1S/4HIO3.Sn/c4*2-1(3)4;/h4*(H,2,3,4);/q;;;;+4/p-4
    Key: WGVVTQUSFDMILB-UHFFFAOYSA-J
  • O=I(=O)O[Sn](OI(=O)=O)(OI(=O)=O)OI(=O)=O
Properties
Sn(IO3)4
Molar mass 818.29
Appearance colourless columnal crystals
Density 5.107 g·cm-3（23 °C[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tin(IV) iodate is an inorganic compound with the chemical formula Sn(IO3)4. It was first obtained in 2020 through the hydrothermal reaction of tin(II) oxide and iodic acid in water at 220 °C.[1] It is a colorless columnar crystal, crystallized in the triclinic P1 space group.[1] It has an indirect band gap (experimental 4.0 eV; calculated 2.75 eV).[2]

References

  1. ^ a b c Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.
  2. ^ Liang, Akun; Rodriguez-Hernandez, Placida; Muñoz, Alfonso; Rahman, Saqib; Segura, Alfredo; Errandonea, Daniel (2021). "Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons". Inorganic Chemistry Frontiers. 8 (22): 4780–4790. doi:10.1039/D1QI00870F. ISSN 2052-1553.
Stub icon

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.