Although an episcopal see of Alessano (Latin: Alexanum) may date from around 700 AD or was probably established under Norman rule around 900 AD, but the regular succession of its bishops began only in 1283 with a Giovanni from Naples. Until the 16th century, papal bulls regarding the bishopric called it either Alexanum or Leuca. It was a suffragan of the Metropolitan of Otranto.
On 17 May 1518, it was suppressed, its territory being merged into the diocese of Lecce under Bishop Giovanni Antonio Acquaviva d'Aragona, but it was restored on 3 June 1521.
Byzantine liturgical usages continued to be observed until abolished by Bishop Ercole Lamia (1578–1591).[3][4]
The existence of the residential see was ended by the papal bull De utiliori of 27 June 1818 of Pope Pius VII, which assigned its territory to the then diocese of Ugento.[5]
Giovanni Belardino Giannelli (1717.12.18 – death 1743)
Archbishop-Bishop Luigi d'Alessandro (1743.07.15 – 1754.09.16), previously Metropolitan Archbishop of Santa Severina (Italy) (1731.05.07 – 1743.07.15); later Metropolitan Archbishop of Bari–Canosa (Italy) (1754.09.16 – death 1770)
Dionigi Latomo (1754.12.16 – 1781)
Gaetano Paolo de Miceli, Ardorini Missionaries (P.O.C.R.) (1792.02.27 – 1804.10.29); later Archbishop of Rossano (Italy) (1804.10.29 – 1813.10.22)
1818 June 27: Suppressed to the Diocese of Ugento[2]
1968: Restored as Titular Episcopal See of Alessano[2]
It has had the following incumbents, of the lowest (episcopal) class, except the first and the latest (who were granted the Personal Title and rank of Archbishop) :
Titular Archbishop Tomás Alberto Clavel Méndez (1968.12.18 – 1978.02.21), as emeritate[clarification needed]; previously Bishop of David (Panama) (1955.07.24 – 1964.03.03), President of Episcopal Conference of Panama (1964–1967), President of Episcopal Secretariat of Central America and Panama (1964–1971), Metropolitan Archbishop of Panamá (Panama) (1964.03.03 – 1968.12.18)
^While Cardinal-Deacon of S. Maria in Cosmedin (1496.03? – 1519.01.21) and then Cardinal-Deacon of S. Maria in Aquiroin commendam (1508.09.26 – 1517.05.25), Luigi d'Aragona was also Apostolic Administrator of Nardò (Italy) (1517.06.17 – 1519.01.21); previously Apostolic Administrator of Lecce (Italy) (1498.12.10 – 1502.03.24), Apostolic Administrator of Policastro (Italy) (1501 – 1504.04.22), Apostolic Administrator of Aversa (Italy) (1501.03.10 – 1515.05.21), Apostolic Administrator of Capaccio (Italy) (1503.01.20 – 1514.03.22), Apostolic Administrator of Cava (Italy) (1511 – 1514.05.05), Apostolic Administrator of Roman Catholic Diocese of Cádiz (Spain) (1511.02.10 – 1511.06.06), Apostolic Administrator of León (Spain) (1511.06.06 – 1516.12.17), Apostolic Administrator of Telese (Italy) (1515)
^While Cardinal-Deacon of S. Adriano al Foro (1517.07.06 – 1537.08.17), Trivulzio was also Apostolic Administrator of Reggio Calabria (Italy) (1520.08.24 – 1520.10.01), Apostolic Administrator of Roman Catholic Diocese of Bobbio (Italy) (1522.09.26 – 1524.05.27), Metropolitan Archbishop of above Reggio Calabria (Italy) (1523.10.01 – 1529), Apostolic Administrator of Toulon (France) (1524.06.22 – 1535.06.07), Apostolic Administrator of Le Puy-en-Velay (France) (1525.09.15 – 1525.10.08), Apostolic Administrator of Avranches (France) (1526.05.02 – 1526.10.19)
Gulik, Guilelmus van; Konrad Eubel (1923). L. Schmitz-Kallenberg (ed.). Hierarchia catholica medii aevi (in Latin). Vol. III (editio altera ed.). Münster: sumptibus et typis librariae Regensbergianae.