Unlike the parent (open-form) oxocarboxylic acid, the pseudoacid has a chiral center.
The position of equilibrium in oxocarboxylic acids, toward the open form or the cyclic (pseuodacid) form, is influenced by a number of factors. In aliphatic 4- and 5-oxocarboxylic acids, intervening substituents assists in ring closure. Alkenes with the interacting groups substituted cis to each other also assists in ring closure. Aryl systems with the interacting groups substituted ortho to each other assists in ring closure. Other factors such as the gem-dialkyl effect (Thorpe–Ingold effect), electronic influences, and steric compression can also influence the open-cyclic equilibrium.
Like carboxylic acids, pseudoacids have "pseudoacyl" derivatives. These include pseudoacyl halides, pseudoesters, endocyclic and exocyclic-N pseudoamides, and pseudoanhydrides. Like aldehydes and ketones, pseudoacids have "pseudocarbonyl" derivatives also.
References
^Bredt, J., 1886. Über Acetyllävulinsäure und die Constitution der γ-Ketonsäuren. Annalen der chemie 236, 225–240.