The album was preceded by its lead single "Ex's & Oh's", which was released on September 23, 2014, and has since peaked at No. 10 on the Billboard Hot 100.[4] It has since been certified double Platinum. "Ex's & Oh's" reached the top of the Alternative Songs chart in September 2015, becoming only the second song by a solo female to reach the top since 1996 after Lorde achieved the feat in 2013 with "Royals". It was also preceded by the promotional single "Under the Influence". The album's second single "America's Sweetheart" was also a commercial success it peaked at no.10 on the Hot Rock & Alternative Songs (Billboard) becoming her second song to do so, it has since been certified platinum in Canada.
The album made history by being the first ever number 1 album on the UK Americana chart, which launched on 28 January 2016.[5] It also was placed No. 2 on UK Biggest Americana Albums of 2016 and has since been certified platinum in the United States.
"Ex's & Oh's" was released on September 23, 2014, as the album's lead single. It first found success in the rock genre, where it became the second song by a solo female artist in the past twenty years to reach the top position of the BillboardAlternative Songs airplay chart[8] and led the magazine's Hot Rock Songs chart for 10 consecutive weeks in mid-2015. The song later crossed over to a mainstream audience and became a number-one hit on the Adult Pop Songs chart in addition to spending one week in the top 10 of the all-genre Billboard Hot 100. "Ex's & Oh's" received two nominations at the 58th Grammy Awards: for Best Rock Performance and Best Rock Song.[9]
"America's Sweetheart" was released on February 8, 2016, as the second mainstream single and third overall released from Love Stuff; it impacted American hot adult contemporary radio on that date.[12]
Marcus Floyd from Renowned for Sound was impressed by King's "sonically versatile qualities" in her vocal performance over the track listing and the lyrical content she co-wrote with her collaborators, saying that "it’s great to hear less clichéd written tracks, replaced by personal pieces that tell a story and relive an experience." He concluded that King's career was just beginning, saying that "with her debut album now under her belt, she seems capable of anything; we can’t wait to hear more from this girl."[14]AllMusic's Stephen Thomas Erlewine was critical of King's vocals feeling exhaustive throughout the album as she keeps up her chosen image but gave praise to her performances on "Ex's & Oh's", "Under the Influence", "Last Damn Night" and "Jackson" for finding a balance between "rock crunch and soul testifying," concluding that "Such highlights suggests that when [Elle] King doesn't have to try so hard to prove her bona fides, she might wind up with a record that's hard to deny. For now, she merely has a promising debut on her hands."[13]