Jack Richard Norton (born May 5, 1945) is an American organometallic chemist and Professor at Columbia University. His research has focused on the studying the reactivity and properties of transition metal hydrides. He coauthored the textbook "Principles and Applications of Organotransition Metal Chemistry."[1]
His laboratory demonstrated the possibility of dinuclear reductive elimination from transition metal alkyls and hydrides by comparing the mechanisms of reductive elimination from (H)2Os(CO)4, (H)(CH3)Os(CO)4, and (CH3)2Os(CO)4. His group later reported some of the first detailed pKa measurements of metal hydrides and demonstrated that the rates of protonation at transition metals can be quite slow.[2] His group has also reported on the use of metal-hydride bonds as radical initiators of cyclization reactions.[3]
In 2005 he received the ACS Award for Organometallic Chemistry[4] and in 2013 the Cope Scholar Award [5]
^Collman, J. P., Hegedus, L. S., Norton, J. R., Finke, R. G., "Principles and Applications of Organotransition Metal Chemistry," University Science Books: Mill Valley, 1987. ISBN9780935702514
^Kramarz, K. W., Norton, J. R., "Slow Proton Transfer Reactions in Organometallic and Bioinorganic Chemistry", Prog. Inorg. Chem. 1994, volume 42, 1. doi:10.1002/9780470166437.ch1
^Kuo, J.L., Hartung, J., Han, A., Norton, J.R., "Direct Generation of Oxygen-Stabilized Radicals by H· Transfer from Transition Metal Hydrides", JACS 2015, volume 137, 3. doi:10.1021/ja511883b