In 1962, she was chosen by Sir Evelyn Dennison Hone, the Governor-General of Northern Rhodesia, to become a member of her country's Legislative Council. She consulted Kenneth Kaunda before accepting.[3]
She then trained for the Foreign Office and rose to be Zambia's Ambassador and Plenipotentiary to Sweden, Denmark, Norway and Finland from 1974 to 1977. From 1977 she was the country's Permanent Representative to the United Nations. In 1979 she became the Permanent Secretary of Zambia's Tourism Ministry.[3] After Kenneth Kaunda lost power she was retained as a diplomat by President Frederick Chiluba until 1997. She was the Zambian Ambassador to Germany.[4]
In 2001, she was a candidate in the 2001 Zambian general election, to be the President of Zambia. She stood for the Social Democratic Party which she formed in August 2000 to concentrate on issues important to women and children.[4][5] One million votes were cast for eleven candidates in the elections. Two of the candidates were women. Konie received more than 10,000 votes and Levy Mwanawasa was elected.[2]
Konie was also a poet. Her poem "In the Fist of your Hatred" was included in The Penguin Book of Modern African Poetry in 2007. The poem is a polemic against male arrogance.[6]
She died at MKP Trust Hospital in Lusaka in 2009 and received a state funeral.[7] President Rupiah Banda said it was a day for Zambia to mourn her death and Kenneth Kaunda noted her involvement with the formation of Zambia following independence from Britain.[8]