A gleysol or gley soil is a hydric soil that unless drained is saturated with groundwater for long enough to develop a characteristic gleyic colour pattern. The pattern is essentially made up of reddish, brownish, or yellowish colours at surfaces of soil particles and/or in the upper soil horizons mixed with greyish/blueish colours inside the peds and/or deeper in the soil. Gleysols are also known as Gleyzems, meadow soils, Aqu-suborders of Entisols, Inceptisols and Mollisols (USDA soil taxonomy), or as groundwater soils and hydro-morphic soils.
The clay on the right is exposed to air and is oxidized a reddish hue. The clay on the left is identical, but sealed in a glass jar for two weeks in an anaerobic setting, causing redox and color change to gley.
Gleysols occupy an estimated 720 million hectares worldwide. They are azonal soils and occur in nearly all climates. The largest extent of Gleysols is in northern Russia, Siberia, Canada, Alaska, China and Bangladesh. An estimated 200 million hectares of gleysols are found in the tropics, mainly in the Amazon region, equatorial Africa, and the coastal swamps of Southeast Asia.
They exhibit a greenish-blue-grey soil color because of anoxicwetland conditions. On exposure, as the iron in the soil oxidizes colors are transformed to a mottled pattern of reddish, yellow or orange patches. During soil formation (gleying), the oxygen supply in the soil profile is restricted due to soil moisture at saturation. Anaerobic micro-organisms support cellular respiration by using alternatives to free oxygen as electron acceptors to support cellular respiration. Where anaerobic organismsreduceferric oxide to ferrous oxide, the reduced mineral compounds produce the typical gleysoil color. Green rust, a layered double hydroxide (LDH) of Fe(II) and Fe(III) can be found as the mineral fougerite in gleysoils.[3][4]
Gleysoils may be sticky and hard to work, especially where the gleying is caused by surface water held up on a slowly permeable layer. However, some ground-water gley soils have permeable lower horizons, including, for example, some sands in hollows within sand dune systems (known as slacks), and in some alluvial situations.
Groundwater gleysoils develop where drainage is poor because the water table (phreatic surface) is high, whilst surface-water gleying occurs when precipitation input at the surface does not drain freely through the ground. A reducing environment exists in the saturated layers, which become mottled greyish-blue or greyish-brown due to its ferrous iron and organic matter content. The presence of reddish or orange mottles indicates localised re-oxidation of ferrous salts in the soil matrix, and is often associated with root channels, animal burrows, or cracking of the soil material during dry spells.
^Trolard F., Bourrié G., Abdelmoula M., Refait P. and Feder F. (2007). Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure. Clays and Clay Minerals, vol. 55, no. 3, p. 323–334; doi:10.1346/CCMN.2007.0550308.
^Génin J.-M. R., Aïssa R., Géhin A., Abdelmoula M., Benali O., Ernstsen V., Ona-Nguema G., Upadhyay Ch. and Ruby Ch. (2005). Fougerite and FeII-III hydroxycarbonate green rust; ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythic ferrosic hydroxide Fe(OH)2+x. Solid State Sciences, vol. 7., no. 5, p. 545–572. doi:10.1016/j.solidstatesciences.2005.02.001.
