She married the banker Nathan Adam von Arnstein, a partner in the firm of Arnstein and Eskeles; her sister Cäcilie von Eskeles was married to the other partner, Bernhard von Eskeles. They brought the social influences of Berlin, notably the concept of the intellectual salon, to the Vienna of Joseph II. The Arnstein mansion at Vienna and her villas at Schönbrunn and Baden bei Wien were regularly used for hospitality. She was also involved in charitable works.