Charoite

Charoite
General
CategorySilicate mineral
Formula
(repeating unit)
K(Ca,Na)
2
Si
4
O
10
(OH,F)•H
2
O
IMA symbolCha[1]
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/m
Identification
ColorViolet, lilac, light brown
Crystal habitFibrous, massive
CleavageGood in three directions
FractureConchoidal
Mohs scale hardness5 - 6
LusterVitreous to pearly
StreakWhite
DiaphaneityTranslucent
Specific gravity2.54 - 2.58
Optical propertiesBiaxial (+)
Refractive indexnα = 1.550
nβ = 1.553
nγ = 1.559
Birefringence0.009
Ultraviolet fluorescenceWeakly fluorescent
Common impuritiesAl, Fe, Mn, Sr, Ba
Other characteristics Radioactive 10.69% (K)
References[2][3][4][5]

Charoite (/ær.t/ CHAR-ow-ait) is a rare silicate mineral with the chemical composition K(Ca,Na)
2
Si
4
O
10
(OH,F)•H
2
O
, first described in 1978. It is named after the Chara River, despite its being 70 kilometres (43 mi) away from the discovery place.[6][3] When it was discovered, it was thought to be a fake, dyed purple to give it its striking appearance.[7]

Properties

Charoite is translucent lavender to purple in color with a pearly luster. Charoite is strictly massive in nature, and fractures are conchoidal. It has an unusual swirling, fibrous appearance, sometimes chatoyant, and that, along with its intense color, can lead many to believe at first that it is synthetic or enhanced artificially. Though reportedly discovered in the 1940s, it was not known to most of the world until its description in 1978. It is said to be opaque and unattractive when found in the field; a fact that may have contributed to its late recognition.[5] Charoite consists of oxygen (43.75%), silicon (27.65%) and calcium (17.53%) mainly, but its composition includes potassium (10.69%) - which gives it its radioactive properties - and hydrogen (0.39%) as well. It has a barely detectable, 0.65% radioactivity concentration per Gamma Ray American Petroleum Institute Units.[3]

Inclusions mainly come in the swirly patterns of the mineral.[8] The black spots on some specimens are either augite or aegirine, the latter occurring in almost all charoites since they commonly grow together. Larger round greenish spots are feldspar. Lighter colored stones or ones with translucent areas are likely due to canasite. The yellowish brown spots are tinaksite, which was discovered at the same time as charoite was. Charoite's silky, fibrous structure results in a shimmery looking polished stone. Sometimes, the very white flashes are tiny white feldspar.[7] Sugilites and charoites can be confused, as both are purple, and sugilite can have black and white inclusions, however sugilite lacks the swirling pattern that are present in charoite stones, and it also lacks the chatoyant effect.[8]

Occurrences

It has been reported only from the Aldan Shield, Sakha Republic, Siberia, Russia. It is found where a syenite of the Murun Massif has intruded into and altered limestone deposits producing a potassium feldspar metasomatite,[5] and forms between 200 - 250 °C.[3] Tinaksite, canasite and charoite are associated and black aegirine is also common where these three minerals grow. Common impurities include aluminium, iron, manganese, strontium and barium.[7] Charoitite is a rock like lapis lazuli, but unlike the latter one, charoitite mostly consists of the mineral charoite.[9]

Marketing and uses

When it arrived to the western market, it was already named charoite. Common tradenames include charoite jade and lilac stone. Although considering its rarity and only type locality, even the highest quality charoite gemstones cost only a few dollars a carat, usually costing between 1.10 - $3 per carat.[9][10] In its price, color and chatoyancy are the main factors. Chatoyant translucent varieties are the most sought after, as while chatoyancy already being uncommon in the mineral, translucent varieties are rarer than the more common opaque ones.[8] Alongside jewelry, due to the fact that the material can be massive in size, charoite can be used in the making of bookends, vases, goblets, boxes, or in small statues. Despite its relatively high hardness, it makes poor center pieces in rings and in bracelets. As it is a heat sensitive mineral, the mechanical cleaning of it should be avoided. It is recommended to use mild detergents and soft brushes or a cloth to clean it, and to never use strong and toxic detergents on it.[8][9]

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Mineralienatlas
  3. ^ a b c d Barthelmy, David (2014). "Charoite Mineral Data". Webmineral.com. Retrieved 2022-04-12.
  4. ^ "Charoite". Mindat.org. Retrieved 4 July 2022.
  5. ^ a b c Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Charoite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Archived from the original (PDF) on 7 November 2022. Retrieved 4 July 2022.
  6. ^ Ian Frazier, Travels in Siberia, Farrar, Straus and Giroux, New York (NY), 2010, ISBN 978-0-374-27872-4, page 394
  7. ^ a b c "Charoite Meaning, History and Detailed Information with Photos". Cape Cod Crystals. Retrieved 2022-04-12.
  8. ^ a b c d "What is Charoite? – A Complete Buying Guide | Jewelry Guide". Retrieved 2022-04-12.
  9. ^ a b c "Charoite Value, Price, and Jewelry Information". International Gem Society. Retrieved 2022-04-12.
  10. ^ "Charoite Information - Gorgeous purple gemstone from Siberia". gemselect.com. Retrieved 2022-04-12.

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