Recorded on 5 December – the last date of Weller's 2005 UK tour – it features live versions of songs spanning his career, including those of The Jam and The Style Council.
Five songs played at the concert were omitted from the CD: Mermaids, Amongst Butterflies, Early Morning Rain, Here's The Good News, and We All Need Love, a duet with The Charlatans' Tim Burgess. Catch-Flame! entered the UK chart at #17 on 18 June 2006.[2]