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This is a list of Roman Catholic bishops of Kyiv. For Greek Catholic bishops of Kyiv, see List of Major Archbishops of Kyiv-Halych.

Roman Catholic bishops of Kyiv diocese include:

• 1320–1334 Henryk, missionary bishop
• 1350–1378 Jakub, missionary bishop
• 1378–1383 Mikołaj, missionary bishop
• Borzysław 1375–1420, missionary bishop
• 1405–1410 Filip
• 1410–1429 Michał Trestka
• 1430 Stanisław z Buzowa
• 1431-? Stanisław Martini
• Andrzej d. 1434
• Jan 1421–1466
• 1449–1473 Klemens 1423–1473
• 1477–1483 Jan
• 1487–1494 Michał
• 1520–1524 Jan Filipowicz 1480–1537
• 1526–1531 Mikołaj Wieżgajło
• 1532–1533 Jerzy Talat
• 1534–1536 Franciszek 1506–1551
• Jan Andruszewicz 1515–1570
• 1564–1572 Mikołaj Pac 1527–1585
• 1592–1598 Józef Wereszczyński 1592–1598
• 1599–1618 Krzysztof Kazimierski 1572–1618
• 1619–1633 Bogusław Radoszewski 1577–1633
• 1633–1635 Andrzej Szołdrski 1633–1635
• 1646–1653 Stanisław Zaremba
• 1655–1656 Jan Leszczyński
• 1656–1677 Tomasz Ujejski
• 1679–1682 Jan Stanisław Witwicki
• 1683–1692 Andrzej Chryzostom Załuski 1650–1711
• Jarosław Sokołowski 1656–1701
• 1697–1699 Mikołaj Święcicki
• 1700–1711 Jan Paweł Sariusz-Gomoliński 1667–1711
• 1715–1718 Walenty Maciej Arcemberski 1674–1717
• 1718–1723 Jan Joachim Tarło
• 1723–1756 Jan Samuel Ożga d. 1756
• 1756–1759 Kajetan Sołtyk 1715–1788
• 1759–1774 Józef Andrzej Załuski 1702–1774
• 1774–1784 Ignacy Franciszek Ossoliński 1730–1784
• 1784–1798 Kasper Cieciszowski 1745–1831

• Jan Purwiński (1991–2011);
• Petro Malchuk (2011–2016);
• Vitaliy Skomarovskyi (apostolic administrator, 2016–2017);
• Vitaliy Kryvytskyi (since 2017).

Notes:

• the above dates are birth-death dates, not office terms.
• Kyiv diocese was created in 1397; in 1798 it was merged with Lutsk diocese forming the Zhytomyr diocese which in 1991 became the diocese of Kyiv-Zhytomyr

• Bishop of Kyiv (disambiguation)
• Ukrainian Catholic Archeparchy of Kyiv