The play-offs of the 2016 Fed Cup Europe/Africa Zone Group I were the final stages of the Group I zonal competition involving teams from Europe and Africa. Using the positions determined in their pools, the fourteen teams faced off to determine their placing in the 2016 Fed Cup Europe/Africa Zone Group I. The top two teams advanced to World Group II play-offs, and the bottom two teams were relegated to the Europe/Africa Zone Group II.

Placing	Pool A	Pool B	Pool C	Pool D
1	Ukraine	Great Britain	Israel	Belgium
2	Portugal	Georgia	Croatia	Bulgaria
3	—	—	Estonia	Latvia
4	Sweden	South Africa	Turkey	Hungary

The first placed teams of each pool were drawn in head-to-head rounds. The winner of each round advanced to the World Group II play-offs.

Belgium 2	Municipal Tennis Centre, Eilat, Israel[1] 6 February 2016 Hard (outdoors)		Great Britain 0
1 2 3 1 Ysaline Bonaventure Katie Swan 6 3 3 6 6 3   2 Alison Van Uytvanck Heather Watson 6 4 3 6 6 4   3 Marie Benoît / An-Sophie Mestach Jocelyn Rae / Anna Smith       not played

Ukraine 3	Municipal Tennis Centre, Eilat, Israel[2] 6 February 2016 Hard (outdoors)		Israel 0
1 2 3 1 Kateryna Bondarenko Shahar Pe'er 6 1 6 1     2 Lesia Tsurenko Julia Glushko 77 61 77 62     3 Kateryna Bondarenko / Olga Savchuk Shelly Krolitzky / Alona Pushkarevsky 6 2 6 2

The runner-up teams from pools B and D and those from A and C competed in order to establish which two teams would place joint fifth in the final standings and which two would place joint seventh.

Georgia 2	Municipal Tennis Centre, Eilat, Israel[3] 6 February 2016 Hard (outdoors)		Bulgaria 1
1 2 3 1 Ekaterine Gorgodze Dia Evtimova 0 6 6 4 6 2   2 Sofia Shapatava Isabella Shinikova 6 1 61 77 4 6   3 Oksana Kalashnikova / Sofia Shapatava Elitsa Kostova / Isabella Shinikova 6 2 4 6 6 4

Portugal 0	Municipal Tennis Centre, Eilat, Israel[4] 6 February 2016 Hard (outdoors)		Croatia 2
1 2 3 1 Maria João Koehler Silvia Njirić 4 6 3 6     2 Michelle Larcher de Brito Ana Konjuh 2 6 2 6     3 Michelle Larcher de Brito / Inês Murta Darija Jurak / Tena Lukas       not played

The teams placing last in each pool competed to keep their place in the Europe/Africa Zone Group I. The bottom-placed team from group A faced the bottom-placed team from Group C, whilst Group B's and Group D's bottom-placed teams faced off. The losers were relegated to the 2016 Europe/Africa Zone Group II.

South Africa 0	Municipal Tennis Centre, Eilat, Israel[5] 6 February 2016 Hard (outdoors)		Hungary 2
1 2 3 1 Ilze Hattingh Anna Bondár 0 6 1 6     2 Chanel Simmonds Réka-Luca Jani 0 6 3 6     3 Michelle Sammons / Chanel Simmonds Dalma Gálfi / Fanny Stollár       not played

Sweden 0	Municipal Tennis Centre, Eilat, Israel[6] 6 February 2016 Hard (outdoors)		Turkey 2
1 2 3 1 Susanne Celik İpek Soylu 3 6 2 6     2 Rebecca Peterson Çağla Büyükakçay 6 2 4 6 0 6   3 Jacqueline Cabaj Awad / Cornelia Lister Çağla Büyükakçay / İpek Soylu       not played

Placing	Teams
Promoted	Belgium	Ukraine
Third	Great Britain	Israel
Fifth	Georgia	Croatia
Seventh	Bulgaria	Portugal
Ninth	Estonia	Latvia
Eleventh	Hungary	Turkey
Relegated	South Africa	Sweden

•  Belgium and  Ukraine advanced to World Group II play-offs.
•  South Africa and  Sweden were relegated to Europe/Africa Group II in 2017.

• Fed Cup website