The seven first qualified after the first half of the 2013–14 ACB regular season qualified to the tournament. As Unicaja, host team, finished between the seven first teams, the eighth qualified joined the Copa del Rey.
The 2014 Copa del Rey de Baloncesto was drawn on 27 January 2014 at approximately 12:00 CET and was broadcast live on YouTube and on TV in many countries.[2] The seeded teams were paired in the quarterfinals with the non-seeded teams. There were not any restrictions for the draw of the semifinals. As in recent season, the first qualified team plays its quarterfinal game on Thursday.