Property of certain fluids to change viscosity over time
In continuum mechanics, time-dependent viscosity is a property of fluids whose viscosity changes as a function of time. The most common type of this is thixotropy, in which the viscosity of fluids under continuous shear decreases with time; the opposite is rheopecty, in which viscosity increases with time.
Some non-Newtonianpseudoplastic fluids show a time-dependent change in viscosity and a non-linear stress-strain behavior in which the longer the fluid undergoes shear stress, the lower its viscosity becomes. A thixotropic fluid is one that takes time to attain viscosity equilibrium when introduced to a step change in shear rate. When shearing in a thixotropic fluid exceeds a certain threshold, it results in a breakdown of the fluid's microstructure and the exhibition of a shear thinning property.
Certain gels or fluids that are thick (viscous) under static conditions will begin to thin and flow as they are shaken, agitated, or otherwise stressed. When stress ceases, they regress to their more viscous state after a passage of time. Some thixotropic fluids return to a gel state almost instantly, such as ketchup, and are called pseudoplastic fluids. Others, such as yogurt, take much longer and can become nearly solid. Many gels and colloids are thixotropic materials, exhibiting a stable form at rest but becoming increasingly fluid when agitated.
Some clays (including bentonite and montmorillonite) exhibit thixotropy, as do certain clay deposits found in caves (slow flowing underground streams tend to layer fine-grained sediment into mudbanks that initially appear dry and solid but then become moist and soupy when dug into or otherwise disturbed). Drilling muds used in geotechnical applications can be thixotropic.
Semi-solid casting processes such as thixomoulding use the thixotropic property of some alloys (mostly light metals, e.g. bismuth) to great advantage. Within certain temperature ranges and with appropriate preparation, these alloys can be injected into molds in a semi-solid state, resulting in a cast with less shrinkage and other superior properties than those cast in normal injection molding processes.
Solder pastes used in electronics manufacturing printing processes are thixotropic.
Many kinds of paints and inks (e.g. the plastisols used in silkscreentextile printing) exhibit thixotropic qualities. In many cases it is desirable for an ink or paint to flow sufficiently fast to form a uniform layer, but then resist further flow (which on vertical surfaces can result in sagging). Thixotropic inks that quickly regain a high viscosity are used in CMYK-type printing processes; this is necessary to protect the structure of the dots for accurate color reproduction.
Basically the mirror of thixotropy, rheopectic fluids are an even rarer class of non-Newtonian fluids that exhibit a time-dependent increase in viscosity; they thicken or solidify when shaken or agitated. The longer they undergo a shearing force, the higher their viscosity becomes, [3] as the microstructure of a rheopectic fluid builds under continuous shearing (possibly due to shear-induced crystallization).
Examples and Applications
Examples of rheopectic fluids include some gypsum pastes, printer inks, and lubricants.
There is also aggressive ongoing research into rheopectic materials especially with regard to potential uses in shock absorption. In addition to obvious potential military applications, rheopectic padding and armor could offer significant advantages over alternative materials currently in use in a wide range of fields from sporting goods and athletic footwear to skydiving and automobile safety.
Additional insights into rheopecty and the possible uses of rheopectic fluids can be gained through further research into the physics of hysteresis.[4]
J. R. Lister and H. A. Stone (1996). Time-dependent viscous deformation of a drop in a rapidly rotating denser fluid. Journal of Fluid Mechanics, 317, pp 275–299 doi:10.1017/S0022112096000754
Reiner, M., and Scott Blair, Rheology terminology, in Rheology, Vol. 4 pp. 461, (New York: Achedemic Press, 1967)