He quit acting to attend Harvard University, which he later described as "just about the most stupid decision" he ever made.[4] Nevertheless, de Carvalho graduated from Harvard and then earned an MBA degree from the same university.[5]
De Carvalho was the vice-chairman of investment banking at Citigroup, where he chaired Citi Private Bank in the EMEA (Europe, Middle East and Africa) region, a post to which he was appointed in November 2009.[7][5]
On 23 April 2015 he became the Executive Director at Heineken Holding N.V., but remains active as board member or director of several other business ventures.[8]
In 2018 Carvalho was appointed chairman of CapGen.[9]
^ abcdSellers, Patricia (3 December 2014). "Heineken's Charlene de Carvalho: A self-made heiress". Fortune Magazine. No. 22 December 2014. Time Inc. Retrieved 30 December 2014. While women in the Netherlands generally attach their maiden name to their married name, Charlene, as a London resident, had dropped "Heineken" from her surname.
^Sellers, Patricia (3 December 2014). "Heineken's Charlene de Carvalho: A self-made heiress". Fortune. Retrieved 3 June 2022. All in the family: How to pass on a company to the next generation. The de Carvalho family (...) Alexander (...) Louisa, Charles, Sophie, and Isabel.