Lutetium(III) selenide

Lutetium(III) selenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.086 Edit this at Wikidata
EC Number
  • 235-308-6
  • InChI=1S/2Lu.3Se/q2*+3;3*-2
    Key: JLNSXPFEELLOLT-UHFFFAOYSA-N
  • [Se-2].[Se-2].[Se-2].[Lu+3].[Lu+3]
Properties
Lu2Se3
Molar mass 586.847 g·mol−1
Appearance grey[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lutetium(III) selenide is an inorganic compound with the chemical formula Lu2Se3.

Preparation

Lutetium(III) selenide can be obtained by reacting lutetium and selenium:

2 Lu + 3 Se → Lu2Se3

It can also be prepared by reacting lutetium oxide and hydrogen selenide at a high temperature:[2]

Lu2O3 + 3 H2Se → Lu2Se3 + 3 H2O

Properties

Lutetium(III) selenide can form orthorhombic AgLuSe2 in the binary system of silver selenide.[3] It can form Lu2PbSe4 and Lu2Pb4Se7 in the binary system of lead selenide.[4]

References

  1. ^ K.-J. Range, Ch. Eglmeier (August 1991). "Crystal data for rare earth sesquiselenides Ln2Se3 (Ln ≡ Ho, Er, Tm, Yb, Lu) and structure refinement of Er2Se3". Journal of the Less Common Metals. 171 (1): L27 – L30. doi:10.1016/0022-5088(91)90254-2. Retrieved 2023-06-13.
  2. ^ Guittard, Micheline; Benacerraf, A.; Flahaut, J. Selenides L2Se3 and L2Se4 of rare earth elements. Ann. Chim. (Paris), 1964. 9 (1-2): 25-34. CAN61: 38017.
  3. ^ Julien-Pouzol, M.; Guittard, M. Crystallochemical study of the ternary silver-rare earth-sulfur or selenium compounds situated along the silver chalcogenide-lanthanide(III) chalcogenide binary systems. Annales de Chimie (Paris, France), 1973. 8 (2): 139-145. ISSN 0151-9107.
  4. ^ Nasibov, I. O.; Sultanov, T. I.; Mardakhaev, B. N. Study of the interaction in the system lutetium selenide(Lu2Se3)-lead selenide. Zhurnal Neorganicheskoi Khimii, 1981. 26 (8): 2263-2264.