Bassett left Birmingham for Arsenal in 2008.[8] She signed for Leeds Carnegie in October 2009[9] and helped the Yorkshire club win the Premier League Cup in February 2010.[10]
After Leeds' funding and FA WSL bid collapsed, Bassett spent a period without a club.[11] In October 2010 it was revealed that she had re-signed for Birmingham City.[12] In April 2012 Bassett was appointed as one of eight digital media ambassadors, one from each team, who wear their Twitter account name on their shirt sleeves to raise the profile of the WSL.[13] At the end of the 2013 season, club captain Bassett rejected Birmingham's offer of a new contract and joined Chelsea.[14]
With Bassett Chelsea finished as runners-up in the 2014 FA WSL, but she signed a three-year contract with Notts County ahead of the 2015 campaign.[15]
Following Notts County's folding in April 2017,[16] Bassett became a free agent. She joined Australian club Canberra United for the 2017–18 Australian W-League season.[17]
Bassett sat out the 2018–19 season to give birth to her daughter Saede. On 3 June 2019 she announced her retirement.[18][19]
Bassett represented England at youth level,[5][7] including at the 2002 FIFA U-19 Women's World Championship. When she made her senior debut against Italy in February 2003,[21] she became the first Birmingham City Ladies player to play for England at full international level.[22]
Under new coach Mark Sampson, Bassett started England's first game at the 2015 FIFA Women's World Cup, a 1–0 defeat by France. She sustained a black eye after being elbowed in the face by Camille Abily, but the French player controversially escaped any punishment.[26] During added time in the semi-final match against Japan, Bassett lobbed the ball into England's goal while trying to clear it to prevent Japan from taking an open shot, resulting in a 2–1 defeat.[27]
Bassett is in a long-term relationship with Manchester United Women manager Marc Skinner, having met while both coaching for Birmingham's U-14s team.[31] Their daughter, Saede, was born in December 2018.[32] Their second child was born in March 2024.[33]