She was a daughter of Gilles II de Laval-Loué and Louise de Sainte-Maure de Neslé.
She married on 14 February 1564 François de Saint-Nectaire, State Councilor and Knight of the Order of the Holy Spirit. They had 5 daughters and 1 son :
Diane, wife of Christophe de Polignac and maid of honor of Queen Louise of Lorraine,
She becomes the mistress of King Henry III of France, who appreciated her for her wit. The King had an emotional attachment towards her.
When she was on her deathbed, the King came to see her one last time.
References
Pierre de L'Estoile, « Mémoires et registre-journal de Henri III, Henri IV et de Louis XIII », 1837