Williams went on to play college basketball at Radford University from 1997 to 2001.[4] During his four-year career, Williams recorded 1,176 points (12.6 per game average), 412 rebounds (4.4), 173 assists (1.9) and 128 steals (1.4).[4] His best season came in 1999–2000 during his junior year. He averaged career-highs of 18.1 points and 6.5 rebounds per game as he led the Highlanders to a 12–2 Big South Conference record.[4][5] They won the conference regular season championship[5] and Williams was named the Big South Conference Player of the Year.[6] Other accolades in college include being a two-time First Team All-Conference player (2000, 2001) and an All-Big South tournament selection (2001).[6]
After college, Williams had a brief stint in the NBA Development League. He appeared in eight games for the Greenville Groove in the late portion of the 2001–02 season.[7] In the 2002 playoffs he appeared in five games; the Groove went on to win the D-League championship.[7][8] In 2008–09 Williams played for Kecskeméti TE, a professional basketball team in Hungary.