Procter was born on October 8, 1968.[1] She was adopted as an infant by William Procter, a general practitioner, and Barbara Jones, a volunteer worker, and raised in Raleigh, North Carolina. She was three years old when her parents divorced. She has an older brother, Whit, who is also adopted.[2]
In 1995, Procter played Annabel, a brief love interest of Joey Tribbiani (Matt LeBlanc), in the second episode of season two of the NBC sitcom Friends, titled "The One with the Breast Milk." From 2000 to 2002 and again in 2006, Procter played the recurring role of Associate White House Counsel Ainsley Hayes in the NBC political drama The West Wing.
Procter played the starring role of Calleigh Duquesne in the CSI spin-off CSI: Miami. The show ran on CBS for 10 seasons, from September 23, 2002, to April 8, 2012.[4][5]
In February 2013, Procter had a recurring role in the final two episodes of season four of the USA Network crime drama White Collar. She played Amanda Callaway, an agent from Atlanta who is promoted to head of the FBI's white collar crimes division in New York City.[7]
Procter has been in a relationship with musician Paul Bryan since 2008. On December 8, 2010, she gave birth to their daughter Philippa Frances (called "Pippa").[10] Because her pregnancy was not written into the ninth season of CSI: Miami, her appearances were limited.[11][12]
Procter has taken part in various triathlons and marathons. She is an avid poker player and has participated in at least one celebrity poker tournament.[13] Procter also sings in a 1980s cover band originally called White Lightning but since renamed Motion.[14] Procter has volunteered with the Young Storytellers Program[15] and at homeless shelters.[16]