In summer 2017, Matović became an assistant coach for Partizan NIS under Miroslav Nikolić.[5][6] In mid-December 2017, Matović was the interim head coach for Partizan following departure of coach Nikolić.[7] On 13 December, he coached the Partizan team in a 83–67 loss to RETAbet Bilbao Basket.[8] On the next day, Matović joined staff of Nenad Čanak who was hired as the new Partizan head coach.[9]
In October 2018, Matović was named the interim head coach for Partizan following departure of coach Čanak.[10] On 31 October, Matović had a 77–72 loss to Turk Telecom.[11][12] Matović finished his second stint as the interim head coach with one lost when new head coach Andrea Trinchieri was hired on 1 November, joining his coaching staff as assistant.[13][6]
On 8 March 2021, Partizan NIS hired Matović as their new head coach for the rest of the 2020–21 season.[14][15] Two days later, he made his official debut in a 75–70 loss to Metropolitans 92.[16][17] Following this lost, Partizan was eliminated in the Top 16 stage of the 2020–21 EuroCup season.[18] He left the head coach position in June 2021, following arrival of the new head coach Željko Obradović.[19] In August, he was named back as an assistant coach for Partizan under Obradović.[20]