The World Group play-offs were four ties which involved the losing nations of the World Group first round and the winning nations of the World Group II. Nations that won their play-off ties entered the 2015 World Group, while losing nations joined the 2015 World Group II.

Participating Teams
Argentina	Canada	France	Poland
Russia	Slovakia	Spain	United States

Russia 4	Adler Arena Skating Center, Sochi, Russia[1] 19–20 April 2014 Clay (indoor)		Argentina 0
1 2 3 1 Elena Vesnina Paula Ormaechea 6 3 6 3     2 Ekaterina Makarova María Irigoyen 7 5 6 1     3 Ekaterina Makarova Paula Ormaechea 6 1 6 2     4 Elena Vesnina María Irigoyen       not played 5 Valeria Solovyeva / Elena Vesnina Victoria Bosio / Nadia Podoroska 6 2 6 1

Canada 3	PEPS, Quebec City, Canada[2] 19–20 April 2014 Hard (Indoor)		Slovakia 1
1 2 3 1 Aleksandra Wozniak Jana Čepelová 4 6 7 5 7 5   2 Eugenie Bouchard Kristína Kučová 77 60 2 6 6 1   3 Eugenie Bouchard Jana Čepelová 78 66 6 3     4 Aleksandra Wozniak Kristína Kučová       not played 5 Gabriela Dabrowski / Sharon Fichman Janette Husárová / Anna Karolína Schmiedlová 4 6 7 5 [9] [11]

United States 2	Chaifetz Arena, St. Louis, United States[3] 19–20 April 2014 Hard (Indoor)		France 3
1 2 3 1 Sloane Stephens Caroline Garcia 3 6 2 6     2 Madison Keys Alizé Cornet 64 77 77 64 6 3   3 Sloane Stephens Virginie Razzano 6 2 6 4     4 Madison Keys Caroline Garcia 4 6 3 6     5 Madison Keys / Sloane Stephens Caroline Garcia / Virginie Razzano 2 6 5 7

Spain 2	Barcelona Tennis Olimpic, Barcelona, Spain[4] 19–20 April 2014 Clay (Outdoor)		Poland 3
1 2 3 1 Sílvia Soler Espinosa Agnieszka Radwańska 2 6 2 6     2 María Teresa Torró Flor Urszula Radwańska 4 6 6 0 6 1   3 María Teresa Torró Flor Agnieszka Radwańska 3 6 2 6     4 Sílvia Soler Espinosa Urszula Radwańska 6 1 6 3     5 Anabel Medina Garrigues / Sílvia Soler Espinosa Agnieszka Radwańska / Alicja Rosolska 4 6 2 6