"(This Ain't) No Thinkin' Thing" is in the key of A minor, with a vocal range from C4 to E5.[2] The verses use a pattern of G-F-C three times, followed by an F and E chord for one bar each. The refrain uses a pattern of Am-F-G-Am twice, followed by C, G, F and E and another Am-F-G-Am progression.[2] The solos between verses are eight bars long, each based on a pair of Am-F-G-Am progressions.[2] Lyrically, the song reflects on the complexity of understanding love and romance.
Critical reception
Kevin John Coyne of Country Universe rated the song "B+", praising Adkins's baritone singing voice and the use of steel guitar.[3]
Music video
The music video for this song features Adkins singing the song with his band at a concert, as well as him performing the song beneath a sunset orange backdrop, with an acoustic guitar. This video was directed by Michael Merriman.
Chart performance
This song debuted at number 44 on the Hot Country Singles & Tracks chart dated January 25, 1997. Having charted for 20 weeks on that chart, it also became his first Number One single on the country chart dated April 5, 1997.[1] It would remain his only Number One hit until ten years later, when he topped the country charts again with "Ladies Love Country Boys."[1]